Abstract
Understanding the structure-property relationship in polymer/layered silicate nanocomposites is of fundamental importance in designing materials with desired properties. To understand these relations in the case of poly(butylene succinate) (PBS)/organically modified layered silicate (OMLS) nanocomposites, we studied the rheological properties of these materials in detail, because the rheological behavior of polymer/OMLS nanocomposites is strongly influenced by their nanostructure and the interfacial characteristics. For this reason, a series of PBS/OMLS nanocomposites were prepared using a simple melt intercalation technique. Two different types of OMLS, montmorillonite (mmt) modified with octadecylammonium chloride and saponite (sap) modified with quaternary hexadecyl tri-n-butylphosphonium bromide, were used for the nanocomposite preparations. The structure of nanocomposites in the nanometer scale was characterized using wide-angle X-ray diffraction (WAXD) analyses and transmission electron microscopy (TEM) observations. A flocculated structure has a strong effect on mechanical properties (both in solid and melts) and various other materials properties.
Original language | English |
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Pages (from-to) | 2355-2367 |
Number of pages | 13 |
Journal | Macromolecules |
Volume | 36 |
Issue number | 7 |
DOIs | |
Publication status | Published - 8 Apr 2003 |
Externally published | Yes |
ASJC Scopus subject areas
- Organic Chemistry
- Polymers and Plastics
- Inorganic Chemistry
- Materials Chemistry