Stereoselective SmI2-mediated conversion of carbohydrates into cyclopentanols

J. J.Cronjé Grové; Cedric W. Holzapfel; D. Bradley G. Williams

doi:10.1016/0040-4039(95)02380-1

Stereoselective SmI₂-mediated conversion of carbohydrates into cyclopentanols

J. J.Cronjé Grové, Cedric W. Holzapfel, D. Bradley G. Williams

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

Carbohydrate derivatives were employed as precursors in the synthesis of stereodefined cyclopentanols. This rapid conversion was effected by a zinc-assisted Grob-fragmentation, followed by a stereocontrolled SmI₂-mediated cyclisation.

Original language	English
Pages (from-to)	1305-1308
Number of pages	4
Journal	Tetrahedron Letters
Volume	37
Issue number	8
DOIs	https://doi.org/10.1016/0040-4039(95)02380-1
Publication status	Published - 19 Feb 1996

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/0040-4039(95)02380-1

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title = "Stereoselective SmI2-mediated conversion of carbohydrates into cyclopentanols",

abstract = "Carbohydrate derivatives were employed as precursors in the synthesis of stereodefined cyclopentanols. This rapid conversion was effected by a zinc-assisted Grob-fragmentation, followed by a stereocontrolled SmI2-mediated cyclisation.",

author = "Grov{\'e}, \{J. J.Cronj{\'e}\} and Holzapfel, \{Cedric W.\} and Williams, \{D. Bradley G.\}",

year = "1996",

month = feb,

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doi = "10.1016/0040-4039(95)02380-1",

language = "English",

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T1 - Stereoselective SmI2-mediated conversion of carbohydrates into cyclopentanols

AU - Grové, J. J.Cronjé

AU - Holzapfel, Cedric W.

AU - Williams, D. Bradley G.

PY - 1996/2/19

Y1 - 1996/2/19

N2 - Carbohydrate derivatives were employed as precursors in the synthesis of stereodefined cyclopentanols. This rapid conversion was effected by a zinc-assisted Grob-fragmentation, followed by a stereocontrolled SmI2-mediated cyclisation.

AB - Carbohydrate derivatives were employed as precursors in the synthesis of stereodefined cyclopentanols. This rapid conversion was effected by a zinc-assisted Grob-fragmentation, followed by a stereocontrolled SmI2-mediated cyclisation.

UR - https://www.scopus.com/pages/publications/0030044238

U2 - 10.1016/0040-4039(95)02380-1

DO - 10.1016/0040-4039(95)02380-1

M3 - Article

AN - SCOPUS:0030044238

SN - 0040-4039

VL - 37

SP - 1305

EP - 1308

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 8

ER -

Stereoselective SmI₂-mediated conversion of carbohydrates into cyclopentanols

Abstract

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