Stereoselective palladium catalyzed cyclization on carbohydrate templates- a route to chiral cyclopentanes and some heterocyclic analogs

G. J. Engelbrech; C. W. Holzapfel

doi:10.1016/S0040-4039(00)71264-0

Stereoselective palladium catalyzed cyclization on carbohydrate templates- a route to chiral cyclopentanes and some heterocyclic analogs

G. J. Engelbrech, C. W. Holzapfel

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

Certain pseudoglycals are shown to be excellent substrates for the palladium catalyzed introduction of unsaturated pendants into the 1-, 2- or 4-positions followed by Pd-mediated cyclization. This methodology provides a ready entry into homochiral substituted cyclopentanes and their heterocyclic analogs.

Original language	English
Pages (from-to)	2161-2164
Number of pages	4
Journal	Tetrahedron Letters
Volume	32
Issue number	19
DOIs	https://doi.org/10.1016/S0040-4039(00)71264-0
Publication status	Published - 6 May 1991

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)71264-0

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title = "Stereoselective palladium catalyzed cyclization on carbohydrate templates- a route to chiral cyclopentanes and some heterocyclic analogs",

abstract = "Certain pseudoglycals are shown to be excellent substrates for the palladium catalyzed introduction of unsaturated pendants into the 1-, 2- or 4-positions followed by Pd-mediated cyclization. This methodology provides a ready entry into homochiral substituted cyclopentanes and their heterocyclic analogs.",

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AU - Engelbrech, G. J.

AU - Holzapfel, C. W.

PY - 1991/5/6

Y1 - 1991/5/6

N2 - Certain pseudoglycals are shown to be excellent substrates for the palladium catalyzed introduction of unsaturated pendants into the 1-, 2- or 4-positions followed by Pd-mediated cyclization. This methodology provides a ready entry into homochiral substituted cyclopentanes and their heterocyclic analogs.

AB - Certain pseudoglycals are shown to be excellent substrates for the palladium catalyzed introduction of unsaturated pendants into the 1-, 2- or 4-positions followed by Pd-mediated cyclization. This methodology provides a ready entry into homochiral substituted cyclopentanes and their heterocyclic analogs.

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U2 - 10.1016/S0040-4039(00)71264-0

DO - 10.1016/S0040-4039(00)71264-0

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 19

ER -

Stereoselective palladium catalyzed cyclization on carbohydrate templates- a route to chiral cyclopentanes and some heterocyclic analogs

Abstract

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