Solvent Transport Characteristics of Thermoplastic Elastomer Blends Based on Nylon and NBR

Jiji Abraham; K. Muraleedharan; C. Radhesh Kumar; Sabu Thomas; Soney C. George

doi:10.1002/pen.24409

Solvent Transport Characteristics of Thermoplastic Elastomer Blends Based on Nylon and NBR

Jiji Abraham
, K. Muraleedharan
, C. Radhesh Kumar
, Sabu Thomas
, Soney C. George

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Transport characteristics of chlorinated hydrocarbon through Nylon/NBR (Acrylonitrile Butadiene Rubber) blend has been investigated with special reference to the effect of blend ratio, compatibilizer and effect of dynamic crosslinking. An attempt has been made to correlate the diffusion characteristics with morphology of the blend. Fine and uniform distribution of the dispersed domains with a stable morphology were obtained by dynamic vulcanization. Depending on the composition, blends show dispersed/matrix and co-continuous phase morphologies. The various transport parameters such as diffusion coefficient (D), permeation coefficient (P) and sorption coefficients (S) were evaluated at different diffusion conditions such as temperature and percentage of compatibilizer. The equilibrium solvent uptake decreases with an increase in the concentration of NBR in the blends. Finally thermodynamic parameters were evaluated from the diffusion data. POLYM. ENG. SCI., 57:231–236, 2017.

Original language	English
Pages (from-to)	231-236
Number of pages	6
Journal	Polymer Engineering and Science
Volume	57
Issue number	2
DOIs	https://doi.org/10.1002/pen.24409
Publication status	Published - 1 Feb 2017
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
Polymers and Plastics
Materials Chemistry

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10.1002/pen.24409

Cite this

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title = "Solvent Transport Characteristics of Thermoplastic Elastomer Blends Based on Nylon and NBR",

abstract = "Transport characteristics of chlorinated hydrocarbon through Nylon/NBR (Acrylonitrile Butadiene Rubber) blend has been investigated with special reference to the effect of blend ratio, compatibilizer and effect of dynamic crosslinking. An attempt has been made to correlate the diffusion characteristics with morphology of the blend. Fine and uniform distribution of the dispersed domains with a stable morphology were obtained by dynamic vulcanization. Depending on the composition, blends show dispersed/matrix and co-continuous phase morphologies. The various transport parameters such as diffusion coefficient (D), permeation coefficient (P) and sorption coefficients (S) were evaluated at different diffusion conditions such as temperature and percentage of compatibilizer. The equilibrium solvent uptake decreases with an increase in the concentration of NBR in the blends. Finally thermodynamic parameters were evaluated from the diffusion data. POLYM. ENG. SCI., 57:231–236, 2017.",

author = "Jiji Abraham and K. Muraleedharan and \{Radhesh Kumar\}, C. and Sabu Thomas and George, \{Soney C.\}",

note = "Publisher Copyright: {\textcopyright} 2016 Society of Plastics Engineers",

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doi = "10.1002/pen.24409",

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TY - JOUR

T1 - Solvent Transport Characteristics of Thermoplastic Elastomer Blends Based on Nylon and NBR

AU - Abraham, Jiji

AU - Muraleedharan, K.

AU - Radhesh Kumar, C.

AU - Thomas, Sabu

AU - George, Soney C.

PY - 2017/2/1

Y1 - 2017/2/1

N2 - Transport characteristics of chlorinated hydrocarbon through Nylon/NBR (Acrylonitrile Butadiene Rubber) blend has been investigated with special reference to the effect of blend ratio, compatibilizer and effect of dynamic crosslinking. An attempt has been made to correlate the diffusion characteristics with morphology of the blend. Fine and uniform distribution of the dispersed domains with a stable morphology were obtained by dynamic vulcanization. Depending on the composition, blends show dispersed/matrix and co-continuous phase morphologies. The various transport parameters such as diffusion coefficient (D), permeation coefficient (P) and sorption coefficients (S) were evaluated at different diffusion conditions such as temperature and percentage of compatibilizer. The equilibrium solvent uptake decreases with an increase in the concentration of NBR in the blends. Finally thermodynamic parameters were evaluated from the diffusion data. POLYM. ENG. SCI., 57:231–236, 2017.

AB - Transport characteristics of chlorinated hydrocarbon through Nylon/NBR (Acrylonitrile Butadiene Rubber) blend has been investigated with special reference to the effect of blend ratio, compatibilizer and effect of dynamic crosslinking. An attempt has been made to correlate the diffusion characteristics with morphology of the blend. Fine and uniform distribution of the dispersed domains with a stable morphology were obtained by dynamic vulcanization. Depending on the composition, blends show dispersed/matrix and co-continuous phase morphologies. The various transport parameters such as diffusion coefficient (D), permeation coefficient (P) and sorption coefficients (S) were evaluated at different diffusion conditions such as temperature and percentage of compatibilizer. The equilibrium solvent uptake decreases with an increase in the concentration of NBR in the blends. Finally thermodynamic parameters were evaluated from the diffusion data. POLYM. ENG. SCI., 57:231–236, 2017.

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U2 - 10.1002/pen.24409

DO - 10.1002/pen.24409

M3 - Article

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SN - 0032-3888

VL - 57

SP - 231

EP - 236

JO - Polymer Engineering and Science

JF - Polymer Engineering and Science

IS - 2

ER -

Solvent Transport Characteristics of Thermoplastic Elastomer Blends Based on Nylon and NBR

Abstract

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