Single-atom catalysts for lithium sulfur batteries via atomic layer deposition process

Lithium-sulfur batteries (LSBs) has emerged as one of the foremost intriguing energy storage systems in the last decade, due to its higher energy density (ED), less expensive, and more environmentally friendly. However, the interface chemistries of electrode–electrolyte such as the shuttling effect of polysulfide and inadequate dynamic sulfur use have not yet been completely understood and managed when in operations, thus the employment of single-atom catalysts (SACs) provides the possibility to address these problems through the proper identification of structure–activity connexions and the chemical reaction processes at the atomic level. In this mini review, the usage of incredibly active SACs is examined with applications in long-lifecycle, higher-energy LSBs, as well as the possibility of SAC preparation using the atomic layer deposition (ALD) process to boost efficiency. Conclusively, the significant problems and future prospects for enhanced SACs via ALD in LSBs development are also discussed.