Silylene-Induced Reduction of [Mn2(CO)10]: Formation of a Five-Coordinate Silicon(IV) Complex with an O-Bound [(OC)4Mn=Mn(CO)4]2–Ligand

Johannes A. Baus; Jordi Poater; F. Matthias Bickelhaupt; Reinhold Tacke

doi:10.1002/ejic.201600913

Silylene-Induced Reduction of [Mn₂(CO)₁₀]: Formation of a Five-Coordinate Silicon(IV) Complex with an O-Bound [(OC)₄Mn=Mn(CO)₄]^2–Ligand

Johannes A. Baus, Jordi Poater, F. Matthias Bickelhaupt, Reinhold Tacke

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

Treatment of the donor-stabilized silylene [iPrNC(NiPr₂)NiPr]₂Si (1) with [Mn₂(CO)₁₀] leads to the five-coordinate silicon(IV) complex 6, accompanied by elimination of two CO molecules. In this redox reaction, the dimanganese fragment is reduced to form an [(OC)₄Mn=Mn(CO)₄]^2–moiety that is coordinated to the silicon(IV) species {[iPrNC(NiPr₂)NiPr]₂Si}²⁺.

Original language	English
Pages (from-to)	186-191
Number of pages	6
Journal	European Journal of Inorganic Chemistry
Volume	2017
Issue number	1
DOIs	https://doi.org/10.1002/ejic.201600913
Publication status	Published - 3 Jan 2017
Externally published	Yes

Keywords

Density functional calculations
Guanidinato ligands
Manganese
Silicon
Silylenes

ASJC Scopus subject areas

Inorganic Chemistry

Access to Document

10.1002/ejic.201600913

Cite this

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title = "Silylene-Induced Reduction of [Mn2(CO)10]: Formation of a Five-Coordinate Silicon(IV) Complex with an O-Bound [(OC)4Mn=Mn(CO)4]2–Ligand",

abstract = "Treatment of the donor-stabilized silylene [iPrNC(NiPr2)NiPr]2Si (1) with [Mn2(CO)10] leads to the five-coordinate silicon(IV) complex 6, accompanied by elimination of two CO molecules. In this redox reaction, the dimanganese fragment is reduced to form an [(OC)4Mn=Mn(CO)4]2–moiety that is coordinated to the silicon(IV) species \{[iPrNC(NiPr2)NiPr]2Si\}2+.",

keywords = "Density functional calculations, Guanidinato ligands, Manganese, Silicon, Silylenes",

author = "Baus, \{Johannes A.\} and Jordi Poater and Bickelhaupt, \{F. Matthias\} and Reinhold Tacke",

note = "Publisher Copyright: {\textcopyright} 2017 WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2017",

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doi = "10.1002/ejic.201600913",

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journal = "European Journal of Inorganic Chemistry",

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T2 - Formation of a Five-Coordinate Silicon(IV) Complex with an O-Bound [(OC)4Mn=Mn(CO)4]2–Ligand

AU - Baus, Johannes A.

AU - Poater, Jordi

AU - Bickelhaupt, F. Matthias

AU - Tacke, Reinhold

PY - 2017/1/3

Y1 - 2017/1/3

N2 - Treatment of the donor-stabilized silylene [iPrNC(NiPr2)NiPr]2Si (1) with [Mn2(CO)10] leads to the five-coordinate silicon(IV) complex 6, accompanied by elimination of two CO molecules. In this redox reaction, the dimanganese fragment is reduced to form an [(OC)4Mn=Mn(CO)4]2–moiety that is coordinated to the silicon(IV) species {[iPrNC(NiPr2)NiPr]2Si}2+.

AB - Treatment of the donor-stabilized silylene [iPrNC(NiPr2)NiPr]2Si (1) with [Mn2(CO)10] leads to the five-coordinate silicon(IV) complex 6, accompanied by elimination of two CO molecules. In this redox reaction, the dimanganese fragment is reduced to form an [(OC)4Mn=Mn(CO)4]2–moiety that is coordinated to the silicon(IV) species {[iPrNC(NiPr2)NiPr]2Si}2+.

KW - Density functional calculations

KW - Guanidinato ligands

KW - Manganese

KW - Silicon

KW - Silylenes

UR - https://www.scopus.com/pages/publications/85007358711

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DO - 10.1002/ejic.201600913

M3 - Article

AN - SCOPUS:85007358711

SN - 1434-1948

VL - 2017

SP - 186

EP - 191

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 1

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