Rhodium(I) metallacycles based on alkylated-PTA scaffolds: Synthesis and evaluation as hydroformylation catalyst precursors

Diteboho S. Ramarou; Banothile C.E. Makhubela; Gregory S. Smith

doi:10.1016/j.ica.2019.119051

Rhodium(I) metallacycles based on alkylated-PTA scaffolds: Synthesis and evaluation as hydroformylation catalyst precursors

Diteboho S. Ramarou, Banothile C.E. Makhubela, Gregory S. Smith

Chemical Sciences

University of Cape Town

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

A series of rhodium(I) metallacycles based on alkylated PTA complexes were synthesised and fully characterised using a range of spectroscopic and analytical techniques. These mononuclear Rh(I) complexes were evaluated in the aqueous biphasic (water-toluene) hydroformylation of 1-octene, showing chemoselectivity to aldehydes.

Original language	English
Article number	119051
Journal	Inorganica Chimica Acta
Volume	496
DOIs	https://doi.org/10.1016/j.ica.2019.119051
Publication status	Published - 1 Oct 2019

Keywords

Alkylated-PTA
Hydroformylation
Metallacycles
Rhodium

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/j.ica.2019.119051

Cite this

@article{d56b5c986c4c40ffa09188859a5d99e6,

title = "Rhodium(I) metallacycles based on alkylated-PTA scaffolds: Synthesis and evaluation as hydroformylation catalyst precursors",

abstract = "A series of rhodium(I) metallacycles based on alkylated PTA complexes were synthesised and fully characterised using a range of spectroscopic and analytical techniques. These mononuclear Rh(I) complexes were evaluated in the aqueous biphasic (water-toluene) hydroformylation of 1-octene, showing chemoselectivity to aldehydes.",

keywords = "Alkylated-PTA, Hydroformylation, Metallacycles, Rhodium",

author = "Ramarou, {Diteboho S.} and Makhubela, {Banothile C.E.} and Smith, {Gregory S.}",

note = "Publisher Copyright: {\textcopyright} 2019 Elsevier B.V.",

year = "2019",

month = oct,

day = "1",

doi = "10.1016/j.ica.2019.119051",

language = "English",

volume = "496",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Rhodium(I) metallacycles based on alkylated-PTA scaffolds

T2 - Synthesis and evaluation as hydroformylation catalyst precursors

AU - Ramarou, Diteboho S.

AU - Makhubela, Banothile C.E.

AU - Smith, Gregory S.

PY - 2019/10/1

Y1 - 2019/10/1

N2 - A series of rhodium(I) metallacycles based on alkylated PTA complexes were synthesised and fully characterised using a range of spectroscopic and analytical techniques. These mononuclear Rh(I) complexes were evaluated in the aqueous biphasic (water-toluene) hydroformylation of 1-octene, showing chemoselectivity to aldehydes.

AB - A series of rhodium(I) metallacycles based on alkylated PTA complexes were synthesised and fully characterised using a range of spectroscopic and analytical techniques. These mononuclear Rh(I) complexes were evaluated in the aqueous biphasic (water-toluene) hydroformylation of 1-octene, showing chemoselectivity to aldehydes.

KW - Alkylated-PTA

KW - Hydroformylation

KW - Metallacycles

KW - Rhodium

UR - http://www.scopus.com/inward/record.url?scp=85070341424&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2019.119051

DO - 10.1016/j.ica.2019.119051

M3 - Article

AN - SCOPUS:85070341424

SN - 0020-1693

VL - 496

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

M1 - 119051

ER -

Rhodium(I) metallacycles based on alkylated-PTA scaffolds: Synthesis and evaluation as hydroformylation catalyst precursors

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this