Research Progress on the Degradation Mechanism and Cycle Stability Improvement of Lithium-Rich Cathode Materials

Ying Zhao, Yi Jia Shao, Luo Qian Li, Jian Wei Ren, Shi Jun Liao

Research output: Contribution to journalArticlepeer-review

Abstract

The lithium-rich cathode material xLi2Mn03 • (1 - x) LiM02 (M = Ni, Co, Mn, etc., 0 < x <1) has the huge advantages of high capacity (up to 300 mA • h/g or more) and low cost, and is known as probably the most important next-generation cathode material for lithium-ion batteries. It has received great attention and extensive research from various countries. At present, this material still has problems such as low initial (first cycle) Coulomb efficiency, poor cycle performance, and serious voltage attenuation, which all seriously hinder the development and practical application of the material In order to solve these problems of this material, especially its insufficient cycle stability and voltage attenuation, a lot of research work has been carried out on the degradation mechanism and stability improvement of the lithium-rich cathode material, and some important progresses have been made in recent years This article introduces the structure and working principle of the lithium-rich cathode material, focusing on the research work in recent years on the degradation mechanism of the lithium-rich cathode material and improving the stability of the lithium-rich cathode material The further research work has been prospected.

Original languageEnglish
Article number1000-0518(2022)02-0205-18
Pages (from-to)205-222
Number of pages18
JournalChinese Journal of Applied Chemistry
Volume39
Issue number2
DOIs
Publication statusPublished - 10 Feb 2022

Keywords

  • Bulk phase doping
  • Degradation mechanism
  • Lithium-ion battery
  • Lithium-rich cathode material
  • Stability improvement
  • Surface coating

ASJC Scopus subject areas

  • General Chemistry
  • Environmental Chemistry
  • Biochemistry
  • General Chemical Engineering
  • Materials Chemistry

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