Remarkable metal-complexed phosphorus analogues of the cyclopropenylcarbene-cyclobutadiene rearrangement

Volodymyr Lyaskovskyy, Niels Elders, Andreas W. Ehlers, Martin Lutz, J. Chris Slootweg, Koop Lammertsma

Research output: Contribution to journalArticlepeer-review

19 Citations (Scopus)

Abstract

In situ-generated metal carbonyl-complexed cyclopropenylphosphinidenes undergo a sequence of structural changes leading to phosphorus analogues of Pettit's seminal (η4-cyclobutadiene)iron tricarbonyl complex via multiple valence isomers along the reaction pathway and the elimination of one molecule of carbon monoxide.

Original languageEnglish
Pages (from-to)9704-9707
Number of pages4
JournalJournal of the American Chemical Society
Volume133
Issue number25
DOIs
Publication statusPublished - 29 Jun 2011
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • General Chemistry
  • Biochemistry
  • Colloid and Surface Chemistry

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