Remarkable metal-complexed phosphorus analogues of the cyclopropenylcarbene-cyclobutadiene rearrangement

Volodymyr Lyaskovskyy; Niels Elders; Andreas W. Ehlers; Martin Lutz; J. Chris Slootweg; Koop Lammertsma

doi:10.1021/ja203083c

Remarkable metal-complexed phosphorus analogues of the cyclopropenylcarbene-cyclobutadiene rearrangement

Volodymyr Lyaskovskyy, Niels Elders, Andreas W. Ehlers, Martin Lutz, J. Chris Slootweg, Koop Lammertsma

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

In situ-generated metal carbonyl-complexed cyclopropenylphosphinidenes undergo a sequence of structural changes leading to phosphorus analogues of Pettit's seminal (η⁴-cyclobutadiene)iron tricarbonyl complex via multiple valence isomers along the reaction pathway and the elimination of one molecule of carbon monoxide.

Original language	English
Pages (from-to)	9704-9707
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	133
Issue number	25
DOIs	https://doi.org/10.1021/ja203083c
Publication status	Published - 29 Jun 2011
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja203083c

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abstract = "In situ-generated metal carbonyl-complexed cyclopropenylphosphinidenes undergo a sequence of structural changes leading to phosphorus analogues of Pettit's seminal (η4-cyclobutadiene)iron tricarbonyl complex via multiple valence isomers along the reaction pathway and the elimination of one molecule of carbon monoxide.",

author = "Volodymyr Lyaskovskyy and Niels Elders and Ehlers, {Andreas W.} and Martin Lutz and Slootweg, {J. Chris} and Koop Lammertsma",

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AU - Lyaskovskyy, Volodymyr

AU - Elders, Niels

AU - Ehlers, Andreas W.

AU - Lutz, Martin

AU - Slootweg, J. Chris

AU - Lammertsma, Koop

PY - 2011/6/29

Y1 - 2011/6/29

N2 - In situ-generated metal carbonyl-complexed cyclopropenylphosphinidenes undergo a sequence of structural changes leading to phosphorus analogues of Pettit's seminal (η4-cyclobutadiene)iron tricarbonyl complex via multiple valence isomers along the reaction pathway and the elimination of one molecule of carbon monoxide.

AB - In situ-generated metal carbonyl-complexed cyclopropenylphosphinidenes undergo a sequence of structural changes leading to phosphorus analogues of Pettit's seminal (η4-cyclobutadiene)iron tricarbonyl complex via multiple valence isomers along the reaction pathway and the elimination of one molecule of carbon monoxide.

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U2 - 10.1021/ja203083c

DO - 10.1021/ja203083c

M3 - Article

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SP - 9704

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 25

ER -

Remarkable metal-complexed phosphorus analogues of the cyclopropenylcarbene-cyclobutadiene rearrangement

Abstract

ASJC Scopus subject areas

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