Regeneration of Degraded Extractant by Sodium Hydroxide Activated Clay and Evaluation of Its Performances in Copper Solvent Extraction

Ruffine Kishiko, Willie Nheta

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

Abstract

In copper solvent extraction, phenolic hydroxy oximes-based extractant has been observed to deteriorate progressively during extraction. Hydrolysis, rather than oxidation or Beckmann rearrangement, produce majority of the degradation products. Degradation products impact the solvent extraction method by lowering extraction efficiency, reaction kinetics, and Cu/Fe selectivity, slowing the phase disengagement time and polluting the electrolyte. Activated clay using sodium hydroxide (NaOH) was used to regenerate deteriorated extractant. After the regeneration step, the organic phase's performance improved: extraction efficiency increased from 67 to 97.3 % maximum, Cu/Fe selectivity increased from 169 to 283 and phase disengagement time decreased from 113 to 88 seconds.

Original languageEnglish
Title of host publicationProceedings of the 8th World Congress on Mechanical, Chemical, and Material Engineering, MCM 2022
EditorsHuihe Qiu, Yuwen Zhang, Marcello Iasiello
PublisherAvestia Publishing
ISBN (Print)9781990800108
DOIs
Publication statusPublished - 2022
Event8th World Congress on Mechanical, Chemical, and Material Engineering, MCM 2022 - Prague, Czech Republic
Duration: 31 Jul 20222 Aug 2022

Publication series

NameProceedings of the World Congress on Mechanical, Chemical, and Material Engineering
ISSN (Electronic)2369-8136

Conference

Conference8th World Congress on Mechanical, Chemical, and Material Engineering, MCM 2022
Country/TerritoryCzech Republic
CityPrague
Period31/07/222/08/22

Keywords

  • Hydroxyoxime
  • LIX 984N
  • activation
  • clay
  • copper solvent extraction
  • degradation
  • extractant
  • regeneration

ASJC Scopus subject areas

  • Mechanical Engineering
  • Mechanics of Materials
  • General Chemical Engineering

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