Reactive intermediates: A transient electrophilic phosphinidene caught in the act

Helen Jansen; Michiel C. Samuels; Erik P.A. Couzijn; J. Chris Slootweg; Andreas W. Ehlers; Peter Chen; Koop Lammertsma

doi:10.1002/chem.200902715

Reactive intermediates: A transient electrophilic phosphinidene caught in the act

Helen Jansen
, Michiel C. Samuels
, Erik P.A. Couzijn
, J. Chris Slootweg
, Andreas W. Ehlers
, Peter Chen
, Koop Lammertsma

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

Trapped! Transient electrophilic phosphinidenes [R-P=W(CO)₅] have emerged as versatile intermediates that are highly valuable in the synthesis of a plethora of organophosphorus compounds, nevertheless their existence has never been unequivocally established. By employing electrospray ionisation tandem mass spectrometry (ESI-MS/MS), this low-valent species has now been detected and its gasphase reactivity perfectly matches the well-established solution-phase data. Figure Equotion

Original language	English
Pages (from-to)	1454-1458
Number of pages	5
Journal	Chemistry - A European Journal
Volume	16
Issue number	5
DOIs	https://doi.org/10.1002/chem.200902715
Publication status	Published - 1 Feb 2010
Externally published	Yes

Keywords

Carbenes
Cycloaddition
Phosphorus
Tungsten

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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10.1002/chem.200902715

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abstract = "Trapped! Transient electrophilic phosphinidenes [R-P=W(CO)5] have emerged as versatile intermediates that are highly valuable in the synthesis of a plethora of organophosphorus compounds, nevertheless their existence has never been unequivocally established. By employing electrospray ionisation tandem mass spectrometry (ESI-MS/MS), this low-valent species has now been detected and its gasphase reactivity perfectly matches the well-established solution-phase data. Figure Equotion",

keywords = "Carbenes, Cycloaddition, Phosphorus, Tungsten",

author = "Helen Jansen and Samuels, \{Michiel C.\} and Couzijn, \{Erik P.A.\} and Slootweg, \{J. Chris\} and Ehlers, \{Andreas W.\} and Peter Chen and Koop Lammertsma",

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doi = "10.1002/chem.200902715",

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T2 - A transient electrophilic phosphinidene caught in the act

AU - Jansen, Helen

AU - Samuels, Michiel C.

AU - Couzijn, Erik P.A.

AU - Slootweg, J. Chris

AU - Ehlers, Andreas W.

AU - Chen, Peter

AU - Lammertsma, Koop

PY - 2010/2/1

Y1 - 2010/2/1

N2 - Trapped! Transient electrophilic phosphinidenes [R-P=W(CO)5] have emerged as versatile intermediates that are highly valuable in the synthesis of a plethora of organophosphorus compounds, nevertheless their existence has never been unequivocally established. By employing electrospray ionisation tandem mass spectrometry (ESI-MS/MS), this low-valent species has now been detected and its gasphase reactivity perfectly matches the well-established solution-phase data. Figure Equotion

AB - Trapped! Transient electrophilic phosphinidenes [R-P=W(CO)5] have emerged as versatile intermediates that are highly valuable in the synthesis of a plethora of organophosphorus compounds, nevertheless their existence has never been unequivocally established. By employing electrospray ionisation tandem mass spectrometry (ESI-MS/MS), this low-valent species has now been detected and its gasphase reactivity perfectly matches the well-established solution-phase data. Figure Equotion

KW - Carbenes

KW - Cycloaddition

KW - Phosphorus

KW - Tungsten

UR - https://www.scopus.com/pages/publications/75749157374

U2 - 10.1002/chem.200902715

DO - 10.1002/chem.200902715

M3 - Article

AN - SCOPUS:75749157374

SN - 0947-6539

VL - 16

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EP - 1458

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 5

ER -

Reactive intermediates: A transient electrophilic phosphinidene caught in the act

Abstract

Keywords

ASJC Scopus subject areas

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