Reactions of bis(η-cyclopentadienyl)vanadium derivatives with dinitrogen oxide (nitrous oxide)

Frank Bottomley; James Darkwa

doi:10.1039/DT9830000399

Reactions of bis(η-cyclopentadienyl)vanadium derivatives with dinitrogen oxide (nitrous oxide)

Frank Bottomley, James Darkwa

University of New Brunswick

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

The reaction between [V(cp)₂(CO)] and N₂O quantitatively gave [{V(cp)₂}_2n(CO₃)_n] where n = 1 or 2. This is analogous to the reaction of [Ti(cp)₂(CO)₂] with N₂O which gave [{Ti(cp)₂}₄(CO₃)₂]. Derivatives of V^III such as [V(cp)₂X] (X = Cl or I) or [V(cp)₂(CO)₂]⁺ did not react with N₂O, although [V(cp)₂X] did react with O₂. The oxidising properties of N₂O are discussed, as are the properties of [{V(Cp)₂}_2n(CO₃)_n].

Original language	English
Pages (from-to)	399-400
Number of pages	2
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	2
DOIs	https://doi.org/10.1039/DT9830000399
Publication status	Published - 1983
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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10.1039/DT9830000399

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title = "Reactions of bis(η-cyclopentadienyl)vanadium derivatives with dinitrogen oxide (nitrous oxide)",

abstract = "The reaction between [V(cp)2(CO)] and N2O quantitatively gave [{V(cp)2}2n(CO3)n] where n = 1 or 2. This is analogous to the reaction of [Ti(cp)2(CO)2] with N2O which gave [{Ti(cp)2}4(CO3)2]. Derivatives of VIII such as [V(cp)2X] (X = Cl or I) or [V(cp)2(CO)2]+ did not react with N2O, although [V(cp)2X] did react with O2. The oxidising properties of N2O are discussed, as are the properties of [{V(Cp)2}2n(CO3)n].",

author = "Frank Bottomley and James Darkwa",

year = "1983",

doi = "10.1039/DT9830000399",

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journal = "Journal of the Chemical Society. Dalton Transactions",

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publisher = "Royal Society of Chemistry",

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T1 - Reactions of bis(η-cyclopentadienyl)vanadium derivatives with dinitrogen oxide (nitrous oxide)

AU - Bottomley, Frank

AU - Darkwa, James

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N2 - The reaction between [V(cp)2(CO)] and N2O quantitatively gave [{V(cp)2}2n(CO3)n] where n = 1 or 2. This is analogous to the reaction of [Ti(cp)2(CO)2] with N2O which gave [{Ti(cp)2}4(CO3)2]. Derivatives of VIII such as [V(cp)2X] (X = Cl or I) or [V(cp)2(CO)2]+ did not react with N2O, although [V(cp)2X] did react with O2. The oxidising properties of N2O are discussed, as are the properties of [{V(Cp)2}2n(CO3)n].

AB - The reaction between [V(cp)2(CO)] and N2O quantitatively gave [{V(cp)2}2n(CO3)n] where n = 1 or 2. This is analogous to the reaction of [Ti(cp)2(CO)2] with N2O which gave [{Ti(cp)2}4(CO3)2]. Derivatives of VIII such as [V(cp)2X] (X = Cl or I) or [V(cp)2(CO)2]+ did not react with N2O, although [V(cp)2X] did react with O2. The oxidising properties of N2O are discussed, as are the properties of [{V(Cp)2}2n(CO3)n].

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DO - 10.1039/DT9830000399

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JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

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ER -

Reactions of bis(η-cyclopentadienyl)vanadium derivatives with dinitrogen oxide (nitrous oxide)

Abstract

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