Reaction of a P/Al-based frustrated lewis pair with ammonia, borane, and amine-boranes: Adduct formation and catalytic dehydrogenation

Christian Appelt; J. Chris Slootweg; Koop Lammertsma; Werner Uhl

doi:10.1002/anie.201208746

Reaction of a P/Al-based frustrated lewis pair with ammonia, borane, and amine-boranes: Adduct formation and catalytic dehydrogenation

Christian Appelt
, J. Chris Slootweg
, Koop Lammertsma
, Werner Uhl

Research output: Contribution to journal › Article › peer-review

142 Citations (Scopus)

Abstract

Open wide! The geminal P/Al-based frustrated Lewis pair (Mes ₂P)(tBu₂Al)Cï£C(H)Ph forms stable Lewis adducts with BH₃ and NH₃. This compound facilitates the dehydrocoupling of the ammonia-borane adduct by unusual N-H bond activation and elimination of dihydrogen at the boron center, and it is a very active main-group-based FLP catalyst for the dehydrogenation of amine-borane H ₃B×NMe₂H. Mes=mesityl.

Original language	English
Pages (from-to)	4256-4259
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	15
DOIs	https://doi.org/10.1002/anie.201208746
Publication status	Published - 8 Apr 2013
Externally published	Yes

Keywords

amine-boranes
dehydrogenation
density functional calculations
frustrated Lewis pairs
homogeneous catalysis

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.201208746

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title = "Reaction of a P/Al-based frustrated lewis pair with ammonia, borane, and amine-boranes: Adduct formation and catalytic dehydrogenation",

abstract = "Open wide! The geminal P/Al-based frustrated Lewis pair (Mes 2P)(tBu2Al)C{\"i}£C(H)Ph forms stable Lewis adducts with BH3 and NH3. This compound facilitates the dehydrocoupling of the ammonia-borane adduct by unusual N-H bond activation and elimination of dihydrogen at the boron center, and it is a very active main-group-based FLP catalyst for the dehydrogenation of amine-borane H 3B×NMe2H. Mes=mesityl.",

keywords = "amine-boranes, dehydrogenation, density functional calculations, frustrated Lewis pairs, homogeneous catalysis",

author = "Christian Appelt and Slootweg, \{J. Chris\} and Koop Lammertsma and Werner Uhl",

year = "2013",

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doi = "10.1002/anie.201208746",

language = "English",

volume = "52",

pages = "4256--4259",

journal = "Angewandte Chemie - International Edition",

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T1 - Reaction of a P/Al-based frustrated lewis pair with ammonia, borane, and amine-boranes

T2 - Adduct formation and catalytic dehydrogenation

AU - Appelt, Christian

AU - Slootweg, J. Chris

AU - Lammertsma, Koop

AU - Uhl, Werner

PY - 2013/4/8

Y1 - 2013/4/8

N2 - Open wide! The geminal P/Al-based frustrated Lewis pair (Mes 2P)(tBu2Al)Cï£C(H)Ph forms stable Lewis adducts with BH3 and NH3. This compound facilitates the dehydrocoupling of the ammonia-borane adduct by unusual N-H bond activation and elimination of dihydrogen at the boron center, and it is a very active main-group-based FLP catalyst for the dehydrogenation of amine-borane H 3B×NMe2H. Mes=mesityl.

AB - Open wide! The geminal P/Al-based frustrated Lewis pair (Mes 2P)(tBu2Al)Cï£C(H)Ph forms stable Lewis adducts with BH3 and NH3. This compound facilitates the dehydrocoupling of the ammonia-borane adduct by unusual N-H bond activation and elimination of dihydrogen at the boron center, and it is a very active main-group-based FLP catalyst for the dehydrogenation of amine-borane H 3B×NMe2H. Mes=mesityl.

KW - amine-boranes

KW - dehydrogenation

KW - density functional calculations

KW - frustrated Lewis pairs

KW - homogeneous catalysis

UR - https://www.scopus.com/pages/publications/84875870727

U2 - 10.1002/anie.201208746

DO - 10.1002/anie.201208746

M3 - Article

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SN - 1433-7851

VL - 52

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 15

ER -

Reaction of a P/Al-based frustrated lewis pair with ammonia, borane, and amine-boranes: Adduct formation and catalytic dehydrogenation

Abstract

Keywords

ASJC Scopus subject areas

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