Preparation of ligand-stabilized [P4O4]2+ by controlled hydrolysis of a janus head type diphosphorus trication

Jan J. Weigand; Kai Oliver Feldmann; Antje K.C. Echterhoff; Andreas W. Ehlers; Koop Lammertsma

doi:10.1002/anie.201001363

Preparation of ligand-stabilized [P4O4]2+ by controlled hydrolysis of a janus head type diphosphorus trication

Jan J. Weigand, Kai Oliver Feldmann, Antje K.C. Echterhoff, Andreas W. Ehlers, Koop Lammertsma

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

A door to new opportunities: The stepwise hydrolysis of a diphosphorus trication is an efficient method for the preparation of an unusual ligand-stabilized dication that contains a novel cationic [P4O4]2+ framework (see Scheme; gray C, blue N, red O, orange P). This approach demonstrates the potential of the diphosphorus trication as a source for phosphorus building blocks to be used in the construction of novel cationic ring and cluster systems.

Original language	English
Pages (from-to)	6178-6181
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	35
DOIs	https://doi.org/10.1002/anie.201001363
Publication status	Published - 16 Aug 2010
Externally published	Yes

Keywords

Cascade reactions
Electrostatic activation
Phosphorus
Polycations
Structure elucidation

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.201001363

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title = "Preparation of ligand-stabilized [P4O4]2+ by controlled hydrolysis of a janus head type diphosphorus trication",

abstract = "A door to new opportunities: The stepwise hydrolysis of a diphosphorus trication is an efficient method for the preparation of an unusual ligand-stabilized dication that contains a novel cationic [P4O4]2+ framework (see Scheme; gray C, blue N, red O, orange P). This approach demonstrates the potential of the diphosphorus trication as a source for phosphorus building blocks to be used in the construction of novel cationic ring and cluster systems.",

keywords = "Cascade reactions, Electrostatic activation, Phosphorus, Polycations, Structure elucidation",

author = "Weigand, {Jan J.} and Feldmann, {Kai Oliver} and Echterhoff, {Antje K.C.} and Ehlers, {Andreas W.} and Koop Lammertsma",

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AU - Weigand, Jan J.

AU - Feldmann, Kai Oliver

AU - Echterhoff, Antje K.C.

AU - Ehlers, Andreas W.

AU - Lammertsma, Koop

PY - 2010/8/16

Y1 - 2010/8/16

N2 - A door to new opportunities: The stepwise hydrolysis of a diphosphorus trication is an efficient method for the preparation of an unusual ligand-stabilized dication that contains a novel cationic [P4O4]2+ framework (see Scheme; gray C, blue N, red O, orange P). This approach demonstrates the potential of the diphosphorus trication as a source for phosphorus building blocks to be used in the construction of novel cationic ring and cluster systems.

AB - A door to new opportunities: The stepwise hydrolysis of a diphosphorus trication is an efficient method for the preparation of an unusual ligand-stabilized dication that contains a novel cationic [P4O4]2+ framework (see Scheme; gray C, blue N, red O, orange P). This approach demonstrates the potential of the diphosphorus trication as a source for phosphorus building blocks to be used in the construction of novel cationic ring and cluster systems.

KW - Cascade reactions

KW - Electrostatic activation

KW - Phosphorus

KW - Polycations

KW - Structure elucidation

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JF - Angewandte Chemie - International Edition

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Preparation of ligand-stabilized [P4O4]2+ by controlled hydrolysis of a janus head type diphosphorus trication

Abstract

Keywords

ASJC Scopus subject areas

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