Preparation, fluxional behaviour, and decomposition of bis(cyclopentadienyl)iodonitrosylvanadium. X-ray crystal structure of [(cpVI)2{cpV(NO)}2(μ-O)4]

Frank Bottomley; James Darkwa; Peter S. White

doi:10.1039/C39820001039

Preparation, fluxional behaviour, and decomposition of bis(cyclopentadienyl)iodonitrosylvanadium. X-ray crystal structure of [(cpVI)₂{cpV(NO)}₂(μ-O)₄]

Frank Bottomley, James Darkwa, Peter S. White

University of New Brunswick

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

cp₂VX(NO) (cp = C₅H₅, X = Br, I) are fluxional molecules in which linear and bent VNO groups interconvert; the molecule with the linear VNO group necessarily contains at least one ring with less than η⁵-hapticity, while cp₂VI(NO) decomposes in vacuo in tetrahydrofuran solution to give [(cpVI)₂{cpV(NO)} ₂(μ-O)₄] whose X-ray crystal structure is reported.

Original language	English
Pages (from-to)	1039-1040
Number of pages	2
Journal	Chemical Communications
Issue number	18
DOIs	https://doi.org/10.1039/C39820001039
Publication status	Published - 1982
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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title = "Preparation, fluxional behaviour, and decomposition of bis(cyclopentadienyl)iodonitrosylvanadium. X-ray crystal structure of [(cpVI)2{cpV(NO)}2(μ-O)4]",

abstract = "cp2VX(NO) (cp = C5H5, X = Br, I) are fluxional molecules in which linear and bent VNO groups interconvert; the molecule with the linear VNO group necessarily contains at least one ring with less than η5-hapticity, while cp2VI(NO) decomposes in vacuo in tetrahydrofuran solution to give [(cpVI)2{cpV(NO)} 2(μ-O)4] whose X-ray crystal structure is reported.",

author = "Frank Bottomley and James Darkwa and White, {Peter S.}",

year = "1982",

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language = "English",

pages = "1039--1040",

journal = "Chemical Communications",

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T1 - Preparation, fluxional behaviour, and decomposition of bis(cyclopentadienyl)iodonitrosylvanadium. X-ray crystal structure of [(cpVI)2{cpV(NO)}2(μ-O)4]

AU - Bottomley, Frank

AU - Darkwa, James

AU - White, Peter S.

PY - 1982

Y1 - 1982

N2 - cp2VX(NO) (cp = C5H5, X = Br, I) are fluxional molecules in which linear and bent VNO groups interconvert; the molecule with the linear VNO group necessarily contains at least one ring with less than η5-hapticity, while cp2VI(NO) decomposes in vacuo in tetrahydrofuran solution to give [(cpVI)2{cpV(NO)} 2(μ-O)4] whose X-ray crystal structure is reported.

AB - cp2VX(NO) (cp = C5H5, X = Br, I) are fluxional molecules in which linear and bent VNO groups interconvert; the molecule with the linear VNO group necessarily contains at least one ring with less than η5-hapticity, while cp2VI(NO) decomposes in vacuo in tetrahydrofuran solution to give [(cpVI)2{cpV(NO)} 2(μ-O)4] whose X-ray crystal structure is reported.

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U2 - 10.1039/C39820001039

DO - 10.1039/C39820001039

M3 - Article

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SN - 0022-4936

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JO - Chemical Communications

JF - Chemical Communications

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ER -

Preparation, fluxional behaviour, and decomposition of bis(cyclopentadienyl)iodonitrosylvanadium. X-ray crystal structure of [(cpVI)₂{cpV(NO)}₂(μ-O)₄]

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