Preorganized frustrated lewis pairs

Federica Bertini; Volodymyr Lyaskovskyy; Brian J.J. Timmer; Frans J.J. De Kanter; Martin Lutz; Andreas W. Ehlers; J. Chris Slootweg; Koop Lammertsma

doi:10.1021/ja210214r

Preorganized frustrated lewis pairs

Federica Bertini, Volodymyr Lyaskovskyy, Brian J.J. Timmer, Frans J.J. De Kanter, Martin Lutz, Andreas W. Ehlers, J. Chris Slootweg, Koop Lammertsma

Research output: Contribution to journal › Article › peer-review

199 Citations (Scopus)

Abstract

Geminal frustrated Lewis pairs (FLPs) are expected to exhibit increased reactivity when the donor and acceptor sites are perfectly aligned. This is shown for reactions of the nonfluorinated FLP tBu ₂PCH ₂BPh ₂ with H ₂, CO ₂, and isocyanates and supported computationally.

Original language	English
Pages (from-to)	201-204
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	134
Issue number	1
DOIs	https://doi.org/10.1021/ja210214r
Publication status	Published - 11 Jan 2012
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja210214r

Cite this

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title = "Preorganized frustrated lewis pairs",

abstract = "Geminal frustrated Lewis pairs (FLPs) are expected to exhibit increased reactivity when the donor and acceptor sites are perfectly aligned. This is shown for reactions of the nonfluorinated FLP tBu 2PCH 2BPh 2 with H 2, CO 2, and isocyanates and supported computationally.",

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AU - Bertini, Federica

AU - Lyaskovskyy, Volodymyr

AU - Timmer, Brian J.J.

AU - De Kanter, Frans J.J.

AU - Lutz, Martin

AU - Ehlers, Andreas W.

AU - Slootweg, J. Chris

AU - Lammertsma, Koop

PY - 2012/1/11

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N2 - Geminal frustrated Lewis pairs (FLPs) are expected to exhibit increased reactivity when the donor and acceptor sites are perfectly aligned. This is shown for reactions of the nonfluorinated FLP tBu 2PCH 2BPh 2 with H 2, CO 2, and isocyanates and supported computationally.

AB - Geminal frustrated Lewis pairs (FLPs) are expected to exhibit increased reactivity when the donor and acceptor sites are perfectly aligned. This is shown for reactions of the nonfluorinated FLP tBu 2PCH 2BPh 2 with H 2, CO 2, and isocyanates and supported computationally.

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Preorganized frustrated lewis pairs

Abstract

ASJC Scopus subject areas

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