Polymorphism in iodotris(tri-p-tolylphosphine)silver(I)

Gertruida J.S. Venter; Andreas Roodt; Reinout Meijboom

doi:10.1107/S0108768109001372

Polymorphism in iodotris(tri-p-tolylphosphine)silver(I)

Gertruida J.S. Venter, Andreas Roodt, Reinout Meijboom

Chemical Sciences

University of The Free State

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The reaction of silver(I) iodide with tri(p-tolyl)phosphine in MeCN solution in 1:3 molar ratio yields a polymorph of the complex of the formula [AgI{P(4-MeC6H4)3}3], with the Ag atom in a distorted tetrahedral environment. A polymorphic structure of this complex (a) is compared with previously published crystal structures (b), determined at different temperatures. The two polymorphs are compared using r.m.s. overlay calculations as well as half-normal probability plots.

Original language	English
Pages (from-to)	182-188
Number of pages	7
Journal	Acta Crystallographica Section B: Structural Science
Volume	65
Issue number	2
DOIs	https://doi.org/10.1107/S0108768109001372
Publication status	Published - 2009

Keywords

Half-normal probability plot
Polymorphism

ASJC Scopus subject areas

General Biochemistry,Genetics and Molecular Biology

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10.1107/S0108768109001372

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abstract = "The reaction of silver(I) iodide with tri(p-tolyl)phosphine in MeCN solution in 1:3 molar ratio yields a polymorph of the complex of the formula [AgI{P(4-MeC6H4)3}3], with the Ag atom in a distorted tetrahedral environment. A polymorphic structure of this complex (a) is compared with previously published crystal structures (b), determined at different temperatures. The two polymorphs are compared using r.m.s. overlay calculations as well as half-normal probability plots.",

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AU - Roodt, Andreas

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AB - The reaction of silver(I) iodide with tri(p-tolyl)phosphine in MeCN solution in 1:3 molar ratio yields a polymorph of the complex of the formula [AgI{P(4-MeC6H4)3}3], with the Ag atom in a distorted tetrahedral environment. A polymorphic structure of this complex (a) is compared with previously published crystal structures (b), determined at different temperatures. The two polymorphs are compared using r.m.s. overlay calculations as well as half-normal probability plots.

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KW - Polymorphism

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ER -

Polymorphism in iodotris(tri-p-tolylphosphine)silver(I)

Abstract

Keywords

ASJC Scopus subject areas

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