Polymerization assisted reduction reaction: A sequential electron-proton transfer reaction catalyzed by gold nanoparticle

Meenakshi Choudhary; Sudheesh K. Shukla; Rafique Ul Islam; Michael J. Witcomb; Cedric Wahl Holzapfel; Kaushik Mallick

doi:10.1021/jp408456c

Polymerization assisted reduction reaction: A sequential electron-proton transfer reaction catalyzed by gold nanoparticle

Meenakshi Choudhary, Sudheesh K. Shukla, Rafique Ul Islam, Michael J. Witcomb, Cedric Wahl Holzapfel, Kaushik Mallick

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

During the polymerization process of aniline (and the derivatives of aniline), the released proton and electron initiate the reduction of 4-nitrophenolate through a proton coupled electron transfer (PCET) mechanism. In situ formation of gold nanoparticles during a similar polymerization process catalyze the reduction reaction.

Original language	English
Pages (from-to)	23009-23016
Number of pages	8
Journal	Journal of Physical Chemistry C
Volume	117
Issue number	44
DOIs	https://doi.org/10.1021/jp408456c
Publication status	Published - 7 Nov 2013

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
General Energy
Physical and Theoretical Chemistry
Surfaces, Coatings and Films

Access to Document

10.1021/jp408456c

Cite this

@article{35a845185a3b40898f982cf007e74986,

title = "Polymerization assisted reduction reaction: A sequential electron-proton transfer reaction catalyzed by gold nanoparticle",

abstract = "During the polymerization process of aniline (and the derivatives of aniline), the released proton and electron initiate the reduction of 4-nitrophenolate through a proton coupled electron transfer (PCET) mechanism. In situ formation of gold nanoparticles during a similar polymerization process catalyze the reduction reaction.",

author = "Meenakshi Choudhary and Shukla, \{Sudheesh K.\} and Islam, \{Rafique Ul\} and Witcomb, \{Michael J.\} and Holzapfel, \{Cedric Wahl\} and Kaushik Mallick",

year = "2013",

month = nov,

day = "7",

doi = "10.1021/jp408456c",

language = "English",

volume = "117",

pages = "23009--23016",

journal = "Journal of Physical Chemistry C",

issn = "1932-7447",

publisher = "American Chemical Society",

number = "44",

}

TY - JOUR

T1 - Polymerization assisted reduction reaction

T2 - A sequential electron-proton transfer reaction catalyzed by gold nanoparticle

AU - Choudhary, Meenakshi

AU - Shukla, Sudheesh K.

AU - Islam, Rafique Ul

AU - Witcomb, Michael J.

AU - Holzapfel, Cedric Wahl

AU - Mallick, Kaushik

PY - 2013/11/7

Y1 - 2013/11/7

N2 - During the polymerization process of aniline (and the derivatives of aniline), the released proton and electron initiate the reduction of 4-nitrophenolate through a proton coupled electron transfer (PCET) mechanism. In situ formation of gold nanoparticles during a similar polymerization process catalyze the reduction reaction.

AB - During the polymerization process of aniline (and the derivatives of aniline), the released proton and electron initiate the reduction of 4-nitrophenolate through a proton coupled electron transfer (PCET) mechanism. In situ formation of gold nanoparticles during a similar polymerization process catalyze the reduction reaction.

UR - https://www.scopus.com/pages/publications/84889877025

U2 - 10.1021/jp408456c

DO - 10.1021/jp408456c

M3 - Article

AN - SCOPUS:84889877025

SN - 1932-7447

VL - 117

SP - 23009

EP - 23016

JO - Journal of Physical Chemistry C

JF - Journal of Physical Chemistry C

IS - 44

ER -

Polymerization assisted reduction reaction: A sequential electron-proton transfer reaction catalyzed by gold nanoparticle

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this