Platinum based mixed-metal clusters (PtnMm(CO)xLy, M = Ru or Os; n + m = 2 to 10 and Ly = other ligands)-Synthesis, structure, reactivity and applications

Akella Sivaramakrishna; Hadley S. Clayton; Banothile C.E. Makhubela; John R. Moss

doi:10.1016/j.ccr.2007.10.007

Platinum based mixed-metal clusters (Pt_nM_m(CO)_xL_y, M = Ru or Os; n + m = 2 to 10 and L_y = other ligands)-Synthesis, structure, reactivity and applications

Akella Sivaramakrishna, Hadley S. Clayton, Banothile C.E. Makhubela, John R. Moss

University of Cape Town

Research output: Contribution to journal › Review article › peer-review

30 Citations (Scopus)

Abstract

This review provides an overview of the synthetic pathways, structure, reactivity and applications of platinum based ruthenium and osmium carbonyl clusters of the types Pt_nRu_m(CO)_xL_y and Pt_nOs_m(CO)_xL_y (where m + n = 2 to 10 and L_y = other ligands). Some important binuclear complexes are also included. The structural aspects of the clusters are briefly discussed. The application of these clusters in organic transformations and catalysis is reviewed and the future prospects are also highlighted.

Original language	English
Pages (from-to)	1460-1485
Number of pages	26
Journal	Coordination Chemistry Reviews
Volume	252
Issue number	12-14
DOIs	https://doi.org/10.1016/j.ccr.2007.10.007
Publication status	Published - Jul 2008
Externally published	Yes

Keywords

Carbonyl clusters
Catalytic applications
Platinum-osmium
Platinum-ruthenium
Structural aspects
Synthetic routes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/j.ccr.2007.10.007

Cite this

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title = "Platinum based mixed-metal clusters (PtnMm(CO)xLy, M = Ru or Os; n + m = 2 to 10 and Ly = other ligands)-Synthesis, structure, reactivity and applications",

abstract = "This review provides an overview of the synthetic pathways, structure, reactivity and applications of platinum based ruthenium and osmium carbonyl clusters of the types PtnRum(CO)xLy and PtnOsm(CO)xLy (where m + n = 2 to 10 and Ly = other ligands). Some important binuclear complexes are also included. The structural aspects of the clusters are briefly discussed. The application of these clusters in organic transformations and catalysis is reviewed and the future prospects are also highlighted.",

keywords = "Carbonyl clusters, Catalytic applications, Platinum-osmium, Platinum-ruthenium, Structural aspects, Synthetic routes",

author = "Akella Sivaramakrishna and Clayton, {Hadley S.} and Makhubela, {Banothile C.E.} and Moss, {John R.}",

year = "2008",

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volume = "252",

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journal = "Coordination Chemistry Reviews",

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}

Platinum based mixed-metal clusters (Pt_nM_m(CO)_xL_y, M = Ru or Os; n + m = 2 to 10 and L_y = other ligands)-Synthesis, structure, reactivity and applications. / Sivaramakrishna, Akella; Clayton, Hadley S.; Makhubela, Banothile C.E. et al.
In: Coordination Chemistry Reviews, Vol. 252, No. 12-14, 07.2008, p. 1460-1485.

Research output: Contribution to journal › Review article › peer-review

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AU - Sivaramakrishna, Akella

AU - Clayton, Hadley S.

AU - Makhubela, Banothile C.E.

AU - Moss, John R.

PY - 2008/7

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AB - This review provides an overview of the synthetic pathways, structure, reactivity and applications of platinum based ruthenium and osmium carbonyl clusters of the types PtnRum(CO)xLy and PtnOsm(CO)xLy (where m + n = 2 to 10 and Ly = other ligands). Some important binuclear complexes are also included. The structural aspects of the clusters are briefly discussed. The application of these clusters in organic transformations and catalysis is reviewed and the future prospects are also highlighted.

KW - Carbonyl clusters

KW - Catalytic applications

KW - Platinum-osmium

KW - Platinum-ruthenium

KW - Structural aspects

KW - Synthetic routes

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