(PH4P)S6 - A compound containing the cyclic radical anion S6·-

Bernhard Neumüller; Fritjof Schmock; Reinhard Kirmse; Andreas Voigt; Axel Diefenbach; F. Matthias Bickelhaupt; Kurt Dehnicke

doi:10.1002/1521-3773(20001215)39:24<4580::AID-ANIE4580>3.0.CO;2-G

(PH₄P)S₆ - A compound containing the cyclic radical anion S₆^·-

Bernhard Neumüller
, Fritjof Schmock
, Reinhard Kirmse
, Andreas Voigt
, Axel Diefenbach
, F. Matthias Bickelhaupt
, Kurt Dehnicke

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Two long S-S bonds link the two S₃ fragments in the cyclic radical anion S₆^·-. This forms as orange-red crystals with PPh₄⁺ as the counterion in the reaction of sulfane with (tetraphenylphosphonium) hydrogen diazide. The anion has a chair conformation with C_2h symmetry (see picture).

Original language	English
Pages (from-to)	4580-4582
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	39
Issue number	24
DOIs	https://doi.org/10.1002/1521-3773(20001215)39:24<4580::AID-ANIE4580>3.0.CO;2-G
Publication status	Published - 15 Dec 2000
Externally published	Yes

Keywords

Ab initio calculations
Density functional calculations
Radical anions
Structure elucidation
Sulfur

ASJC Scopus subject areas

Catalysis
General Chemistry

Access to Document

10.1002/1521-3773(20001215)39:24<4580::AID-ANIE4580>3.0.CO;2-G

Cite this

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title = "(PH4P)S6 - A compound containing the cyclic radical anion S6·-",

abstract = "Two long S-S bonds link the two S3 fragments in the cyclic radical anion S6·-. This forms as orange-red crystals with PPh4+ as the counterion in the reaction of sulfane with (tetraphenylphosphonium) hydrogen diazide. The anion has a chair conformation with C2h symmetry (see picture).",

keywords = "Ab initio calculations, Density functional calculations, Radical anions, Structure elucidation, Sulfur",

author = "Bernhard Neum{\"u}ller and Fritjof Schmock and Reinhard Kirmse and Andreas Voigt and Axel Diefenbach and \{Matthias Bickelhaupt\}, F. and Kurt Dehnicke",

year = "2000",

month = dec,

day = "15",

doi = "10.1002/1521-3773(20001215)39:24<4580::AID-ANIE4580>3.0.CO;2-G",

language = "English",

volume = "39",

pages = "4580--4582",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "24",

}

TY - JOUR

T1 - (PH4P)S6 - A compound containing the cyclic radical anion S6·-

AU - Neumüller, Bernhard

AU - Schmock, Fritjof

AU - Kirmse, Reinhard

AU - Voigt, Andreas

AU - Diefenbach, Axel

AU - Matthias Bickelhaupt, F.

AU - Dehnicke, Kurt

PY - 2000/12/15

Y1 - 2000/12/15

N2 - Two long S-S bonds link the two S3 fragments in the cyclic radical anion S6·-. This forms as orange-red crystals with PPh4+ as the counterion in the reaction of sulfane with (tetraphenylphosphonium) hydrogen diazide. The anion has a chair conformation with C2h symmetry (see picture).

AB - Two long S-S bonds link the two S3 fragments in the cyclic radical anion S6·-. This forms as orange-red crystals with PPh4+ as the counterion in the reaction of sulfane with (tetraphenylphosphonium) hydrogen diazide. The anion has a chair conformation with C2h symmetry (see picture).

KW - Ab initio calculations

KW - Density functional calculations

KW - Radical anions

KW - Structure elucidation

KW - Sulfur

UR - https://www.scopus.com/pages/publications/0034671559

U2 - 10.1002/1521-3773(20001215)39:24<4580::AID-ANIE4580>3.0.CO;2-G

DO - 10.1002/1521-3773(20001215)39:24<4580::AID-ANIE4580>3.0.CO;2-G

M3 - Article

AN - SCOPUS:0034671559

SN - 1433-7851

VL - 39

SP - 4580

EP - 4582

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 24

ER -