TY - JOUR
T1 - Photodegradation of eosin yellow dye in water under simulated solar light irradiation using La–doped ZnO nanostructure decorated on graphene oxide as an advanced photocatalyst
AU - Oppong, Samuel Osei Bonsu
AU - Anku, William Wilson
AU - Opoku, Francis
AU - Shukla, Sudheesh Kumar
AU - Govender, Penny Poomani
N1 - Publisher Copyright:
© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
PY - 2018/1
Y1 - 2018/1
N2 - Organic pollutants from the industries and anthropogenic sources pose severe problems to both the environment and human health. Hence, there is the need to eliminate these pollutants from our water bodies, as safe drinking water is a major prerequisite for healthy life and also as precious resources for human civilisation. In this study, a photocatalyst (La-ZnO-GO) with improved photocatalytic properties is synthesised using co-precipitation approach. The photocatalytic activities, morphologies and structures of the photocatalyst are investigated by means of advanced technologies such as Ultraviolet-Visible spectroscopy, X-ray diffraction, Raman spectroscopy, transmission electron microscopy, scanning electron microscopy. Under visible light irradiation, Eosin Yellow (EY) dye was used to calculate the photocatalytic behaviour of La-ZnOGO composite. The photocatalytic outcome shows that the 0.3% La-ZnO-GO photocatalyst displayed a better photoactivity towards the degradation of organic pollutant. This effective photodegradation of EY dye solution is ascribed to the mutual effect of La and graphene oxide, as well as the improved visible light absorbance and the separation of electron-hole pairs. The total organic carbon result shows a significant mineralisation of EY dye, which drops the formation of potentially harmful degradation by-products. The stability results show a recyclability of the 0.3% La-ZnO-GO composites with 89% degradation efficiency after the five (5) cycles.
AB - Organic pollutants from the industries and anthropogenic sources pose severe problems to both the environment and human health. Hence, there is the need to eliminate these pollutants from our water bodies, as safe drinking water is a major prerequisite for healthy life and also as precious resources for human civilisation. In this study, a photocatalyst (La-ZnO-GO) with improved photocatalytic properties is synthesised using co-precipitation approach. The photocatalytic activities, morphologies and structures of the photocatalyst are investigated by means of advanced technologies such as Ultraviolet-Visible spectroscopy, X-ray diffraction, Raman spectroscopy, transmission electron microscopy, scanning electron microscopy. Under visible light irradiation, Eosin Yellow (EY) dye was used to calculate the photocatalytic behaviour of La-ZnOGO composite. The photocatalytic outcome shows that the 0.3% La-ZnO-GO photocatalyst displayed a better photoactivity towards the degradation of organic pollutant. This effective photodegradation of EY dye solution is ascribed to the mutual effect of La and graphene oxide, as well as the improved visible light absorbance and the separation of electron-hole pairs. The total organic carbon result shows a significant mineralisation of EY dye, which drops the formation of potentially harmful degradation by-products. The stability results show a recyclability of the 0.3% La-ZnO-GO composites with 89% degradation efficiency after the five (5) cycles.
KW - Doped-ZnO
KW - Eosin yellow
KW - Graphene oxide
KW - Lanthanide
UR - http://www.scopus.com/inward/record.url?scp=85045854089&partnerID=8YFLogxK
U2 - 10.1002/slct.201702470
DO - 10.1002/slct.201702470
M3 - Article
AN - SCOPUS:85045854089
SN - 2365-6549
VL - 3
SP - 1180
EP - 1188
JO - ChemistrySelect
JF - ChemistrySelect
IS - 4
ER -