Phosphepines: Convenient access to phosphinidene complexes

Mark L.G. Borst; Rosa E. Bulo; Christiaan W. Winkel; Danièle J. Gibney; Andreas W. Ehlers; Marius Schakel; Martin Lutz; Anthony L. Spek; Koop Lammertsma

doi:10.1021/ja050817y

Phosphepines: Convenient access to phosphinidene complexes

Mark L.G. Borst
, Rosa E. Bulo
, Christiaan W. Winkel
, Danièle J. Gibney
, Andreas W. Ehlers
, Marius Schakel
, Martin Lutz
, Anthony L. Spek
, Koop Lammertsma

Chemical Sciences

Research output: Contribution to journal › Article › peer-review

72 Citations (Scopus)

Abstract

Reaction of o-diethynylbenzene with transition metal-complexed primary phosphines gives in a single base-induced step stable phosphepine complexes as confirmed by X-ray data. At 75-80 °C these phosphepines undergo clean cheletropic elimination of naphthalene to give transient carbene-like phosphinidene complexes that can be trapped in high yield by alkenes, alkynes, and alcohols.

Original language	English
Pages (from-to)	5800-5801
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	127
Issue number	16
DOIs	https://doi.org/10.1021/ja050817y
Publication status	Published - 27 Apr 2005

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

Access to Document

10.1021/ja050817y

Cite this

@article{86e160e58c09437a832f5c4b3e6d672e,

title = "Phosphepines: Convenient access to phosphinidene complexes",

abstract = "Reaction of o-diethynylbenzene with transition metal-complexed primary phosphines gives in a single base-induced step stable phosphepine complexes as confirmed by X-ray data. At 75-80 °C these phosphepines undergo clean cheletropic elimination of naphthalene to give transient carbene-like phosphinidene complexes that can be trapped in high yield by alkenes, alkynes, and alcohols.",

author = "Borst, \{Mark L.G.\} and Bulo, \{Rosa E.\} and Winkel, \{Christiaan W.\} and Gibney, \{Dani{\`e}le J.\} and Ehlers, \{Andreas W.\} and Marius Schakel and Martin Lutz and Spek, \{Anthony L.\} and Koop Lammertsma",

year = "2005",

month = apr,

day = "27",

doi = "10.1021/ja050817y",

language = "English",

volume = "127",

pages = "5800--5801",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "16",

}

TY - JOUR

T1 - Phosphepines

T2 - Convenient access to phosphinidene complexes

AU - Borst, Mark L.G.

AU - Bulo, Rosa E.

AU - Winkel, Christiaan W.

AU - Gibney, Danièle J.

AU - Ehlers, Andreas W.

AU - Schakel, Marius

AU - Lutz, Martin

AU - Spek, Anthony L.

AU - Lammertsma, Koop

PY - 2005/4/27

Y1 - 2005/4/27

N2 - Reaction of o-diethynylbenzene with transition metal-complexed primary phosphines gives in a single base-induced step stable phosphepine complexes as confirmed by X-ray data. At 75-80 °C these phosphepines undergo clean cheletropic elimination of naphthalene to give transient carbene-like phosphinidene complexes that can be trapped in high yield by alkenes, alkynes, and alcohols.

AB - Reaction of o-diethynylbenzene with transition metal-complexed primary phosphines gives in a single base-induced step stable phosphepine complexes as confirmed by X-ray data. At 75-80 °C these phosphepines undergo clean cheletropic elimination of naphthalene to give transient carbene-like phosphinidene complexes that can be trapped in high yield by alkenes, alkynes, and alcohols.

UR - https://www.scopus.com/pages/publications/17744397747

U2 - 10.1021/ja050817y

DO - 10.1021/ja050817y

M3 - Article

AN - SCOPUS:17744397747

SN - 0002-7863

VL - 127

SP - 5800

EP - 5801

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 16

ER -

Phosphepines: Convenient access to phosphinidene complexes

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this