Phosphepines: Convenient access to phosphinidene complexes

Mark L.G. Borst; Rosa E. Bulo; Christiaan W. Winkel; Danièle J. Gibney; Andreas W. Ehlers; Marius Schakel; Martin Lutz; Anthony L. Spek; Koop Lammertsma

doi:10.1021/ja050817y

Phosphepines: Convenient access to phosphinidene complexes

Mark L.G. Borst, Rosa E. Bulo, Christiaan W. Winkel, Danièle J. Gibney, Andreas W. Ehlers, Marius Schakel, Martin Lutz, Anthony L. Spek, Koop Lammertsma

Chemical Sciences

Research output: Contribution to journal › Article › peer-review

69 Citations (Scopus)

Abstract

Reaction of o-diethynylbenzene with transition metal-complexed primary phosphines gives in a single base-induced step stable phosphepine complexes as confirmed by X-ray data. At 75-80 °C these phosphepines undergo clean cheletropic elimination of naphthalene to give transient carbene-like phosphinidene complexes that can be trapped in high yield by alkenes, alkynes, and alcohols.

Original language	English
Pages (from-to)	5800-5801
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	127
Issue number	16
DOIs	https://doi.org/10.1021/ja050817y
Publication status	Published - 27 Apr 2005

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja050817y

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@article{86e160e58c09437a832f5c4b3e6d672e,

title = "Phosphepines: Convenient access to phosphinidene complexes",

abstract = "Reaction of o-diethynylbenzene with transition metal-complexed primary phosphines gives in a single base-induced step stable phosphepine complexes as confirmed by X-ray data. At 75-80 °C these phosphepines undergo clean cheletropic elimination of naphthalene to give transient carbene-like phosphinidene complexes that can be trapped in high yield by alkenes, alkynes, and alcohols.",

author = "Borst, {Mark L.G.} and Bulo, {Rosa E.} and Winkel, {Christiaan W.} and Gibney, {Dani{\`e}le J.} and Ehlers, {Andreas W.} and Marius Schakel and Martin Lutz and Spek, {Anthony L.} and Koop Lammertsma",

year = "2005",

month = apr,

day = "27",

doi = "10.1021/ja050817y",

language = "English",

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TY - JOUR

T1 - Phosphepines

T2 - Convenient access to phosphinidene complexes

AU - Borst, Mark L.G.

AU - Bulo, Rosa E.

AU - Winkel, Christiaan W.

AU - Gibney, Danièle J.

AU - Ehlers, Andreas W.

AU - Schakel, Marius

AU - Lutz, Martin

AU - Spek, Anthony L.

AU - Lammertsma, Koop

PY - 2005/4/27

Y1 - 2005/4/27

N2 - Reaction of o-diethynylbenzene with transition metal-complexed primary phosphines gives in a single base-induced step stable phosphepine complexes as confirmed by X-ray data. At 75-80 °C these phosphepines undergo clean cheletropic elimination of naphthalene to give transient carbene-like phosphinidene complexes that can be trapped in high yield by alkenes, alkynes, and alcohols.

AB - Reaction of o-diethynylbenzene with transition metal-complexed primary phosphines gives in a single base-induced step stable phosphepine complexes as confirmed by X-ray data. At 75-80 °C these phosphepines undergo clean cheletropic elimination of naphthalene to give transient carbene-like phosphinidene complexes that can be trapped in high yield by alkenes, alkynes, and alcohols.

UR - http://www.scopus.com/inward/record.url?scp=17744397747&partnerID=8YFLogxK

U2 - 10.1021/ja050817y

DO - 10.1021/ja050817y

M3 - Article

AN - SCOPUS:17744397747

SN - 0002-7863

VL - 127

SP - 5800

EP - 5801

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 16

ER -

Phosphepines: Convenient access to phosphinidene complexes

Abstract

ASJC Scopus subject areas

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