Phosphaspiropentene as a transient intermediate

J. Chris Slootweg; Willem Jan Van Zeist; Frans J.J. De Kanter; Marius Schakel; Andreas W. Ehlers; Martin Lutz; Anthony L. Spek; Koop Lammertsma

doi:10.1021/om050530+

Phosphaspiropentene as a transient intermediate

J. Chris Slootweg
, Willem Jan Van Zeist
, Frans J.J. De Kanter
, Marius Schakel
, Andreas W. Ehlers
, Martin Lutz
, Anthony L. Spek
, Koop Lammertsma

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

A phosphaspiropentene is the plausible kinetic product from the addition of dichlorocarbene to a phosphatriafulvene, which rearranges to a novel P-substituted triafulvene. The calculated barrier of 18.6 kcal mol^-1 for this process is consistent with the temperature of -40 °C at which this reaction proceeds.

Original language	English
Pages (from-to)	5172-5175
Number of pages	4
Journal	Organometallics
Volume	24
Issue number	21
DOIs	https://doi.org/10.1021/om050530+
Publication status	Published - 10 Oct 2005
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om050530+

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title = "Phosphaspiropentene as a transient intermediate",

abstract = "A phosphaspiropentene is the plausible kinetic product from the addition of dichlorocarbene to a phosphatriafulvene, which rearranges to a novel P-substituted triafulvene. The calculated barrier of 18.6 kcal mol-1 for this process is consistent with the temperature of -40 °C at which this reaction proceeds.",

author = "Slootweg, \{J. Chris\} and \{Van Zeist\}, \{Willem Jan\} and \{De Kanter\}, \{Frans J.J.\} and Marius Schakel and Ehlers, \{Andreas W.\} and Martin Lutz and Spek, \{Anthony L.\} and Koop Lammertsma",

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T1 - Phosphaspiropentene as a transient intermediate

AU - Slootweg, J. Chris

AU - Van Zeist, Willem Jan

AU - De Kanter, Frans J.J.

AU - Schakel, Marius

AU - Ehlers, Andreas W.

AU - Lutz, Martin

AU - Spek, Anthony L.

AU - Lammertsma, Koop

PY - 2005/10/10

Y1 - 2005/10/10

N2 - A phosphaspiropentene is the plausible kinetic product from the addition of dichlorocarbene to a phosphatriafulvene, which rearranges to a novel P-substituted triafulvene. The calculated barrier of 18.6 kcal mol-1 for this process is consistent with the temperature of -40 °C at which this reaction proceeds.

AB - A phosphaspiropentene is the plausible kinetic product from the addition of dichlorocarbene to a phosphatriafulvene, which rearranges to a novel P-substituted triafulvene. The calculated barrier of 18.6 kcal mol-1 for this process is consistent with the temperature of -40 °C at which this reaction proceeds.

UR - https://www.scopus.com/pages/publications/27144536916

U2 - 10.1021/om050530+

DO - 10.1021/om050530+

M3 - Article

AN - SCOPUS:27144536916

SN - 0276-7333

VL - 24

SP - 5172

EP - 5175

JO - Organometallics

JF - Organometallics

IS - 21

ER -

Phosphaspiropentene as a transient intermediate

Abstract

ASJC Scopus subject areas

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