Phosphaspiropentene as a transient intermediate

J. Chris Slootweg; Willem Jan Van Zeist; Frans J.J. De Kanter; Marius Schakel; Andreas W. Ehlers; Martin Lutz; Anthony L. Spek; Koop Lammertsma

doi:10.1021/om050530+

Phosphaspiropentene as a transient intermediate

J. Chris Slootweg, Willem Jan Van Zeist, Frans J.J. De Kanter, Marius Schakel, Andreas W. Ehlers, Martin Lutz, Anthony L. Spek, Koop Lammertsma

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

A phosphaspiropentene is the plausible kinetic product from the addition of dichlorocarbene to a phosphatriafulvene, which rearranges to a novel P-substituted triafulvene. The calculated barrier of 18.6 kcal mol^-1 for this process is consistent with the temperature of -40 °C at which this reaction proceeds.

Original language	English
Pages (from-to)	5172-5175
Number of pages	4
Journal	Organometallics
Volume	24
Issue number	21
DOIs	https://doi.org/10.1021/om050530+
Publication status	Published - 10 Oct 2005
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om050530+

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abstract = "A phosphaspiropentene is the plausible kinetic product from the addition of dichlorocarbene to a phosphatriafulvene, which rearranges to a novel P-substituted triafulvene. The calculated barrier of 18.6 kcal mol-1 for this process is consistent with the temperature of -40 °C at which this reaction proceeds.",

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AU - Slootweg, J. Chris

AU - Van Zeist, Willem Jan

AU - De Kanter, Frans J.J.

AU - Schakel, Marius

AU - Ehlers, Andreas W.

AU - Lutz, Martin

AU - Spek, Anthony L.

AU - Lammertsma, Koop

PY - 2005/10/10

Y1 - 2005/10/10

N2 - A phosphaspiropentene is the plausible kinetic product from the addition of dichlorocarbene to a phosphatriafulvene, which rearranges to a novel P-substituted triafulvene. The calculated barrier of 18.6 kcal mol-1 for this process is consistent with the temperature of -40 °C at which this reaction proceeds.

AB - A phosphaspiropentene is the plausible kinetic product from the addition of dichlorocarbene to a phosphatriafulvene, which rearranges to a novel P-substituted triafulvene. The calculated barrier of 18.6 kcal mol-1 for this process is consistent with the temperature of -40 °C at which this reaction proceeds.

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DO - 10.1021/om050530+

M3 - Article

AN - SCOPUS:27144536916

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SP - 5172

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JO - Organometallics

JF - Organometallics

IS - 21

ER -

Phosphaspiropentene as a transient intermediate

Abstract

ASJC Scopus subject areas

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