Phospha-scorpionate complexes by click chemistry using phenyl azide and ethynylphosphine oxides

Sander G.A. Van Assema; Cornelis G.J. Tazelaar; G. De Bas Jong; Jan H. Van Maarseveen; Marius Schakel; Martin Lutz; Anthony L. Spek; J. Chris Slootweg; Koop Lammertsma

doi:10.1021/om800127h

Phospha-scorpionate complexes by click chemistry using phenyl azide and ethynylphosphine oxides

Sander G.A. Van Assema
, Cornelis G.J. Tazelaar
, G. De Bas Jong
, Jan H. Van Maarseveen
, Marius Schakel
, Martin Lutz
, Anthony L. Spek
, J. Chris Slootweg
, Koop Lammertsma

Research output: Contribution to journal › Article › peer-review

48 Citations (Scopus)

Abstract

The copper-catalyzed Click reaction of phenyl azide with ethynylphosphine oxides provides new P-substituted triazoles. With tris(ethynyl)phosphine oxide this route affords a versatile scorpionate ligand that coordinates to RhCl ₃ as a tripodal N ligand. Upon reduction, the same ligand can act as a P donor to W(CO)₅. Both coordination modes can be combined, giving access to a bimetallic Mo/W complex.

Original language	English
Pages (from-to)	3210-3215
Number of pages	6
Journal	Organometallics
Volume	27
Issue number	13
DOIs	https://doi.org/10.1021/om800127h
Publication status	Published - 14 Jul 2008
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om800127h

Cite this

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title = "Phospha-scorpionate complexes by click chemistry using phenyl azide and ethynylphosphine oxides",

abstract = "The copper-catalyzed Click reaction of phenyl azide with ethynylphosphine oxides provides new P-substituted triazoles. With tris(ethynyl)phosphine oxide this route affords a versatile scorpionate ligand that coordinates to RhCl 3 as a tripodal N ligand. Upon reduction, the same ligand can act as a P donor to W(CO)5. Both coordination modes can be combined, giving access to a bimetallic Mo/W complex.",

author = "\{Van Assema\}, \{Sander G.A.\} and Tazelaar, \{Cornelis G.J.\} and \{De Bas Jong\}, G. and \{Van Maarseveen\}, \{Jan H.\} and Marius Schakel and Martin Lutz and Spek, \{Anthony L.\} and \{Chris Slootweg\}, J. and Koop Lammertsma",

year = "2008",

month = jul,

day = "14",

doi = "10.1021/om800127h",

language = "English",

volume = "27",

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journal = "Organometallics",

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TY - JOUR

T1 - Phospha-scorpionate complexes by click chemistry using phenyl azide and ethynylphosphine oxides

AU - Van Assema, Sander G.A.

AU - Tazelaar, Cornelis G.J.

AU - De Bas Jong, G.

AU - Van Maarseveen, Jan H.

AU - Schakel, Marius

AU - Lutz, Martin

AU - Spek, Anthony L.

AU - Chris Slootweg, J.

AU - Lammertsma, Koop

PY - 2008/7/14

Y1 - 2008/7/14

N2 - The copper-catalyzed Click reaction of phenyl azide with ethynylphosphine oxides provides new P-substituted triazoles. With tris(ethynyl)phosphine oxide this route affords a versatile scorpionate ligand that coordinates to RhCl 3 as a tripodal N ligand. Upon reduction, the same ligand can act as a P donor to W(CO)5. Both coordination modes can be combined, giving access to a bimetallic Mo/W complex.

AB - The copper-catalyzed Click reaction of phenyl azide with ethynylphosphine oxides provides new P-substituted triazoles. With tris(ethynyl)phosphine oxide this route affords a versatile scorpionate ligand that coordinates to RhCl 3 as a tripodal N ligand. Upon reduction, the same ligand can act as a P donor to W(CO)5. Both coordination modes can be combined, giving access to a bimetallic Mo/W complex.

UR - https://www.scopus.com/pages/publications/47949100134

U2 - 10.1021/om800127h

DO - 10.1021/om800127h

M3 - Article

AN - SCOPUS:47949100134

SN - 0276-7333

VL - 27

SP - 3210

EP - 3215

JO - Organometallics

JF - Organometallics

IS - 13

ER -

Phospha-scorpionate complexes by click chemistry using phenyl azide and ethynylphosphine oxides

Abstract

ASJC Scopus subject areas

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