Phospha-scorpionate complexes by click chemistry using phenyl azide and ethynylphosphine oxides

Sander G.A. Van Assema; Cornelis G.J. Tazelaar; G. De Bas Jong; Jan H. Van Maarseveen; Marius Schakel; Martin Lutz; Anthony L. Spek; J. Chris Slootweg; Koop Lammertsma

doi:10.1021/om800127h

Phospha-scorpionate complexes by click chemistry using phenyl azide and ethynylphosphine oxides

Sander G.A. Van Assema, Cornelis G.J. Tazelaar, G. De Bas Jong, Jan H. Van Maarseveen, Marius Schakel, Martin Lutz, Anthony L. Spek, J. Chris Slootweg, Koop Lammertsma

Research output: Contribution to journal › Article › peer-review

46 Citations (Scopus)

Abstract

The copper-catalyzed Click reaction of phenyl azide with ethynylphosphine oxides provides new P-substituted triazoles. With tris(ethynyl)phosphine oxide this route affords a versatile scorpionate ligand that coordinates to RhCl ₃ as a tripodal N ligand. Upon reduction, the same ligand can act as a P donor to W(CO)₅. Both coordination modes can be combined, giving access to a bimetallic Mo/W complex.

Original language	English
Pages (from-to)	3210-3215
Number of pages	6
Journal	Organometallics
Volume	27
Issue number	13
DOIs	https://doi.org/10.1021/om800127h
Publication status	Published - 14 Jul 2008
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om800127h

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title = "Phospha-scorpionate complexes by click chemistry using phenyl azide and ethynylphosphine oxides",

abstract = "The copper-catalyzed Click reaction of phenyl azide with ethynylphosphine oxides provides new P-substituted triazoles. With tris(ethynyl)phosphine oxide this route affords a versatile scorpionate ligand that coordinates to RhCl 3 as a tripodal N ligand. Upon reduction, the same ligand can act as a P donor to W(CO)5. Both coordination modes can be combined, giving access to a bimetallic Mo/W complex.",

author = "{Van Assema}, {Sander G.A.} and Tazelaar, {Cornelis G.J.} and {De Bas Jong}, G. and {Van Maarseveen}, {Jan H.} and Marius Schakel and Martin Lutz and Spek, {Anthony L.} and {Chris Slootweg}, J. and Koop Lammertsma",

year = "2008",

month = jul,

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doi = "10.1021/om800127h",

language = "English",

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journal = "Organometallics",

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T1 - Phospha-scorpionate complexes by click chemistry using phenyl azide and ethynylphosphine oxides

AU - Van Assema, Sander G.A.

AU - Tazelaar, Cornelis G.J.

AU - De Bas Jong, G.

AU - Van Maarseveen, Jan H.

AU - Schakel, Marius

AU - Lutz, Martin

AU - Spek, Anthony L.

AU - Chris Slootweg, J.

AU - Lammertsma, Koop

PY - 2008/7/14

Y1 - 2008/7/14

N2 - The copper-catalyzed Click reaction of phenyl azide with ethynylphosphine oxides provides new P-substituted triazoles. With tris(ethynyl)phosphine oxide this route affords a versatile scorpionate ligand that coordinates to RhCl 3 as a tripodal N ligand. Upon reduction, the same ligand can act as a P donor to W(CO)5. Both coordination modes can be combined, giving access to a bimetallic Mo/W complex.

AB - The copper-catalyzed Click reaction of phenyl azide with ethynylphosphine oxides provides new P-substituted triazoles. With tris(ethynyl)phosphine oxide this route affords a versatile scorpionate ligand that coordinates to RhCl 3 as a tripodal N ligand. Upon reduction, the same ligand can act as a P donor to W(CO)5. Both coordination modes can be combined, giving access to a bimetallic Mo/W complex.

UR - http://www.scopus.com/inward/record.url?scp=47949100134&partnerID=8YFLogxK

U2 - 10.1021/om800127h

DO - 10.1021/om800127h

M3 - Article

AN - SCOPUS:47949100134

SN - 0276-7333

VL - 27

SP - 3210

EP - 3215

JO - Organometallics

JF - Organometallics

IS - 13

ER -

Phospha-scorpionate complexes by click chemistry using phenyl azide and ethynylphosphine oxides

Abstract

ASJC Scopus subject areas

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