Palladium-polymer nanocomposite: An anode catalyst for the electrochemical oxidation of methanol

Samarjeet Siwal; Sophy Matseke; Siyasanga Mpelane; Nishu Hooda; Debkumar Nandi; Kaushik Mallick

doi:10.1016/j.ijhydene.2017.03.033

Palladium-polymer nanocomposite: An anode catalyst for the electrochemical oxidation of methanol

Samarjeet Siwal
, Sophy Matseke
, Siyasanga Mpelane
, Nishu Hooda
, Debkumar Nandi
, Kaushik Mallick

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

54 Citations (Scopus)

Abstract

Polymer supported palladium nanoparticles has been synthesized using an ‘in-situ polymerization and composite formation’ method, where potassium tetrachloropalladate was used as the precursor of palladium nanoparticles. The resultant material was characterized by optical and surface characterization techniques, which offered the information about the chemistry of metal and polymer, whereas, the microscopic characterization showed the morphology of the composite and the orientation of the metal nanoparticles within the polymer matrix. The synthesized material was successfully used as an electrocatalyst for the methanol oxidation reaction in alkaline media.

Original language	English
Pages (from-to)	23599-23605
Number of pages	7
Journal	International Journal of Hydrogen Energy
Volume	42
Issue number	37
DOIs	https://doi.org/10.1016/j.ijhydene.2017.03.033
Publication status	Published - 14 Sept 2017

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Anode catalyst
Methanol oxidation
Polymer supported palladium

ASJC Scopus subject areas

Renewable Energy, Sustainability and the Environment
Fuel Technology
Condensed Matter Physics
Energy Engineering and Power Technology

Access to Document

10.1016/j.ijhydene.2017.03.033

Cite this

@article{1449f600970647e6ac4a7d155ad4ad2d,

title = "Palladium-polymer nanocomposite: An anode catalyst for the electrochemical oxidation of methanol",

abstract = "Polymer supported palladium nanoparticles has been synthesized using an {\textquoteleft}in-situ polymerization and composite formation{\textquoteright} method, where potassium tetrachloropalladate was used as the precursor of palladium nanoparticles. The resultant material was characterized by optical and surface characterization techniques, which offered the information about the chemistry of metal and polymer, whereas, the microscopic characterization showed the morphology of the composite and the orientation of the metal nanoparticles within the polymer matrix. The synthesized material was successfully used as an electrocatalyst for the methanol oxidation reaction in alkaline media.",

keywords = "Anode catalyst, Methanol oxidation, Polymer supported palladium",

author = "Samarjeet Siwal and Sophy Matseke and Siyasanga Mpelane and Nishu Hooda and Debkumar Nandi and Kaushik Mallick",

note = "Publisher Copyright: {\textcopyright} 2017 Hydrogen Energy Publications LLC",

year = "2017",

month = sep,

day = "14",

doi = "10.1016/j.ijhydene.2017.03.033",

language = "English",

volume = "42",

pages = "23599--23605",

journal = "International Journal of Hydrogen Energy",

issn = "0360-3199",

publisher = "Elsevier Ltd.",

number = "37",

}

TY - JOUR

T1 - Palladium-polymer nanocomposite

T2 - An anode catalyst for the electrochemical oxidation of methanol

AU - Siwal, Samarjeet

AU - Matseke, Sophy

AU - Mpelane, Siyasanga

AU - Hooda, Nishu

AU - Nandi, Debkumar

AU - Mallick, Kaushik

PY - 2017/9/14

Y1 - 2017/9/14

N2 - Polymer supported palladium nanoparticles has been synthesized using an ‘in-situ polymerization and composite formation’ method, where potassium tetrachloropalladate was used as the precursor of palladium nanoparticles. The resultant material was characterized by optical and surface characterization techniques, which offered the information about the chemistry of metal and polymer, whereas, the microscopic characterization showed the morphology of the composite and the orientation of the metal nanoparticles within the polymer matrix. The synthesized material was successfully used as an electrocatalyst for the methanol oxidation reaction in alkaline media.

AB - Polymer supported palladium nanoparticles has been synthesized using an ‘in-situ polymerization and composite formation’ method, where potassium tetrachloropalladate was used as the precursor of palladium nanoparticles. The resultant material was characterized by optical and surface characterization techniques, which offered the information about the chemistry of metal and polymer, whereas, the microscopic characterization showed the morphology of the composite and the orientation of the metal nanoparticles within the polymer matrix. The synthesized material was successfully used as an electrocatalyst for the methanol oxidation reaction in alkaline media.

KW - Anode catalyst

KW - Methanol oxidation

KW - Polymer supported palladium

UR - https://www.scopus.com/pages/publications/85016720564

U2 - 10.1016/j.ijhydene.2017.03.033

DO - 10.1016/j.ijhydene.2017.03.033

M3 - Article

AN - SCOPUS:85016720564

SN - 0360-3199

VL - 42

SP - 23599

EP - 23605

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

IS - 37

ER -

Palladium-polymer nanocomposite: An anode catalyst for the electrochemical oxidation of methanol

Abstract

UN SDGs

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this