Palladium-catalysed cyclisation and functionalisation of 1,1-diacetoxy- 2,7-diene and 1,1-diacetoxy-2-en-7-yne derivatives

Cedric W. Holzapfel; Lizel Marais

doi:10.1016/S0040-4039(98)00169-5

Palladium-catalysed cyclisation and functionalisation of 1,1-diacetoxy- 2,7-diene and 1,1-diacetoxy-2-en-7-yne derivatives

Cedric W. Holzapfel, Lizel Marais

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

The palladium-catalysed 'metallo-ene' cyclisation, cyclisation/carbonylation, -vinylstannane coupling, and Pd(II)-catalysed chloropalladation/carbocyclisation of 1,1-diacetoxy-2,7-diene and 1,1- diacetoxy-2-en-7-yne derivatives are described. The cyclic enolacetate products could readily be convened into the corresponding aldehydes that are amenable to further transformation.

Original language	English
Pages (from-to)	2179-2182
Number of pages	4
Journal	Tetrahedron Letters
Volume	39
Issue number	15
DOIs	https://doi.org/10.1016/S0040-4039(98)00169-5
Publication status	Published - 9 Apr 1998

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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title = "Palladium-catalysed cyclisation and functionalisation of 1,1-diacetoxy- 2,7-diene and 1,1-diacetoxy-2-en-7-yne derivatives",

abstract = "The palladium-catalysed 'metallo-ene' cyclisation, cyclisation/carbonylation, -vinylstannane coupling, and Pd(II)-catalysed chloropalladation/carbocyclisation of 1,1-diacetoxy-2,7-diene and 1,1- diacetoxy-2-en-7-yne derivatives are described. The cyclic enolacetate products could readily be convened into the corresponding aldehydes that are amenable to further transformation.",

author = "Holzapfel, {Cedric W.} and Lizel Marais",

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AU - Holzapfel, Cedric W.

AU - Marais, Lizel

PY - 1998/4/9

Y1 - 1998/4/9

N2 - The palladium-catalysed 'metallo-ene' cyclisation, cyclisation/carbonylation, -vinylstannane coupling, and Pd(II)-catalysed chloropalladation/carbocyclisation of 1,1-diacetoxy-2,7-diene and 1,1- diacetoxy-2-en-7-yne derivatives are described. The cyclic enolacetate products could readily be convened into the corresponding aldehydes that are amenable to further transformation.

AB - The palladium-catalysed 'metallo-ene' cyclisation, cyclisation/carbonylation, -vinylstannane coupling, and Pd(II)-catalysed chloropalladation/carbocyclisation of 1,1-diacetoxy-2,7-diene and 1,1- diacetoxy-2-en-7-yne derivatives are described. The cyclic enolacetate products could readily be convened into the corresponding aldehydes that are amenable to further transformation.

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VL - 39

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ER -

Palladium-catalysed cyclisation and functionalisation of 1,1-diacetoxy- 2,7-diene and 1,1-diacetoxy-2-en-7-yne derivatives

Abstract

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