Palladium-catalysed cyclisation and functionalisation of 1,1-diacetoxy- 2,7-diene and 1,1-diacetoxy-2-en-7-yne derivatives

Cedric W. Holzapfel, Lizel Marais

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17 Citations (Scopus)

Abstract

The palladium-catalysed 'metallo-ene' cyclisation, cyclisation/carbonylation, -vinylstannane coupling, and Pd(II)-catalysed chloropalladation/carbocyclisation of 1,1-diacetoxy-2,7-diene and 1,1- diacetoxy-2-en-7-yne derivatives are described. The cyclic enolacetate products could readily be convened into the corresponding aldehydes that are amenable to further transformation.

Original languageEnglish
Pages (from-to)2179-2182
Number of pages4
JournalTetrahedron Letters
Volume39
Issue number15
DOIs
Publication statusPublished - 9 Apr 1998

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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