Organic acid-catalyzed hydrolysis of magnesium hydride for generation of hydrogen in a batch system hydrogen reactor

Joshua Adeniyi Adeniran, Esther Titilayo Akinlabi, Hong Sheng Chen, Romeo Fono-Tamo, Tien Chien Jen

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

5 Citations (Scopus)

Abstract

Hydrogen generation from MgH2 is of interest to the research community due to various alluring attributes of MgH2 as a hydrogen generation substrate. In this study MgH2 powder was utilized as a substrate in hydrolysis reaction catalyzed by acetic acid, an environmentally friendly and relatively cheap acid. The reaction was conducted in a hydrogen generation reactor operated in a batch mode. Three sample weights (0.4g, 0.8g and 1.2g) of the substrates were utilized for the experiment at 40, 50, 60 and 70 wt% acetic acid concentration at 50 °C for investigation of the roles of substrate weigh and catalyst concentration on hydrogen yield. The results indicated that MgH2 powder weight influenced hydrogen generation more compared to the catalyst concentration. The highest hydrogen yield in the study was 0.048 L hydrogen gas from 0.4g MgH2 powder (70 wt% acetic acid) while the highest hydrogen generation was reported when 1.2g substrate hydrolyzed in 50 wt% acetic acid.

Original languageEnglish
Title of host publicationProceedings of the World Congress on Engineering and Computer Science 2017, WCECS 2017
EditorsS. I. Ao, W. S. Grundfest, Craig Douglas
PublisherNewswood Limited
Pages615-619
Number of pages5
ISBN (Print)9789881404848
Publication statusPublished - 2017
Event2017 World Congress on Engineering and Computer Science, WCECS 2017 - San Francisco, United States
Duration: 25 Oct 201727 Oct 2017

Publication series

NameLecture Notes in Engineering and Computer Science
Volume2
ISSN (Print)2078-0958

Conference

Conference2017 World Congress on Engineering and Computer Science, WCECS 2017
Country/TerritoryUnited States
CitySan Francisco
Period25/10/1727/10/17

Keywords

  • Hydrogen generation
  • Hydrolysis
  • Kinetics
  • Magnesium hydride
  • Thermodynamics

ASJC Scopus subject areas

  • Computer Science (miscellaneous)

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