Optimizing the energy values of solid biofuel through acidic pre-treatment: An evolutionary-based neuro-fuzzy modelling and feature importance analysis

The increasing focus on sustainable energy solutions and eco-friendly fuel alternatives has sparked interest in exploring methods to enhance the energy content of solid biofuels through pre-treatment processes. This study investigates the impact of acidic (H₂SO₄) pretreatment on the energy content of solid biofuel derived from watermelon peel waste using machine learning methods. The biofuel properties, and calorific value (CV) were determined experimentally for both H₂SO₄-treated and untreated biofuel samples. Subsequently, an Adaptive neuro-fuzzy inference system (ANFIS) model with Genetic Algorithm (GA) and Grid Partitioning (GP) clustering techniques was developed to predict heating value of the biofuel, with performance evaluation based on root mean square error (RMSE), mean absolute percentage error (MAPE), mean absolute deviation (MAD), Mean Absolute Error (MAE) and R²-values. The decision tree regressor was employed to evaluate the feature importance, predictive power and impact of each input variable on CV prediction based on Gini importance metrics. To establish its superior performance, the hybrid ANFIS-GA-GP model was compared with ordinary-ANFIS and ANN model using same metrics. Results show that acid-pretreatment increased the CV of the solid biofuel by 3.53 MJ/kg (31.83 % improvement) and reduced ash content by 1.77 %. FTIR analysis revealed surface modifications, and a shift in the C-O vibrational stretch, while SEM micrographs displayed denser surfaces and reduced porosity as indicated by a lesser fiber diameter in treated samples. The GP-clustered ANFIS-GA model with a triangular membership function (tri-MF) exhibited superior performance and higher accuracy (RMSE of 0.1309, MAPE of 9.343, MAD of 0.1036, MAE of 0.1110, and R²-value of 0.9773 at model training). Furthermore, a tree decision regressor identified Fixed carbon as the most significant predictor for CV with a Gini importance of 0.988375. This study demonstrates the substantial enhancement in the energy content of biofuel using acidic pre-treatment and insights into a cutting-edge approach of improving the combustion properties of solid biofuel with machine learning models. This significantly contributes to the field of sustainable bioenergy research.