One-pot SmI2-promoted transformation of carbohydrate derivatives into cyclopentanols

J. J.Cronjé Grové; Cedric W. Holzapfel; D. Bradley G. Williams

doi:10.1016/0040-4039(96)01234-8

One-pot SmI₂-promoted transformation of carbohydrate derivatives into cyclopentanols

J. J.Cronjé Grové, Cedric W. Holzapfel, D. Bradley G. Williams

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

41 Citations (Scopus)

Abstract

Selectively functionalised carbohydrate derivatives underwent SmI₂-promoted Grob-fragmentation reactions. This was followed by an in situ, stereocontrolled SmI₂-mediated cyclisation to afford the corresponding cyclopentanols.

Original language	English
Pages (from-to)	5817-5820
Number of pages	4
Journal	Tetrahedron Letters
Volume	37
Issue number	32
DOIs	https://doi.org/10.1016/0040-4039(96)01234-8
Publication status	Published - 5 Aug 1996

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/0040-4039(96)01234-8

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@article{887f32639f21476da5d6ca9b596c7bc7,

title = "One-pot SmI2-promoted transformation of carbohydrate derivatives into cyclopentanols",

abstract = "Selectively functionalised carbohydrate derivatives underwent SmI2-promoted Grob-fragmentation reactions. This was followed by an in situ, stereocontrolled SmI2-mediated cyclisation to afford the corresponding cyclopentanols.",

author = "Grov{\'e}, {J. J.Cronj{\'e}} and Holzapfel, {Cedric W.} and Williams, {D. Bradley G.}",

year = "1996",

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doi = "10.1016/0040-4039(96)01234-8",

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T1 - One-pot SmI2-promoted transformation of carbohydrate derivatives into cyclopentanols

AU - Grové, J. J.Cronjé

AU - Holzapfel, Cedric W.

AU - Williams, D. Bradley G.

PY - 1996/8/5

Y1 - 1996/8/5

N2 - Selectively functionalised carbohydrate derivatives underwent SmI2-promoted Grob-fragmentation reactions. This was followed by an in situ, stereocontrolled SmI2-mediated cyclisation to afford the corresponding cyclopentanols.

AB - Selectively functionalised carbohydrate derivatives underwent SmI2-promoted Grob-fragmentation reactions. This was followed by an in situ, stereocontrolled SmI2-mediated cyclisation to afford the corresponding cyclopentanols.

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U2 - 10.1016/0040-4039(96)01234-8

DO - 10.1016/0040-4039(96)01234-8

M3 - Article

AN - SCOPUS:0030570848

SN - 0040-4039

VL - 37

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EP - 5820

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 32

ER -

One-pot SmI₂-promoted transformation of carbohydrate derivatives into cyclopentanols

Abstract

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