Olefin cycloadditions of the electrophilic phosphinidene complex [iPr2N-P=Fe(CO)4]

Jan B.M. Wit; Gerno T. Van Eijkel; Franciscus J.J. De Kanter; Marius Schakel; Andreas W. Ehlers; Martin Lutz; Anthony L. Spek; Koop Lammertsma

doi:10.1002/(SICI)1521-3773(19990903)38:17<2596::AID-ANIE2596>3.0.CO;2-I

Olefin cycloadditions of the electrophilic phosphinidene complex [iPr₂N-P=Fe(CO)₄]

Jan B.M. Wit, Gerno T. Van Eijkel, Franciscus J.J. De Kanter, Marius Schakel, Andreas W. Ehlers, Martin Lutz, Anthony L. Spek, Koop Lammertsma

Vrije Universiteit Amsterdam

Research output: Contribution to journal › Article › peer-review

59 Citations (Scopus)

Abstract

Highly strained methylenephosphiranes are formed in the reaction of the new electrophilic phosphinidene complex [iPr₂N-P = Fe(CO)₄] with allenes. Remarkably, reaction with diallenes at 0 °C also leads to a phosphirane, which rearranges upon warming to room temperature to a bis- isopropylidenephospholene (see scheme).

Original language	English
Pages (from-to)	2596-2599
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	38
Issue number	17
DOIs	https://doi.org/10.1002/(SICI)1521-3773(19990903)38:17<2596::AID-ANIE2596>3.0.CO;2-I
Publication status	Published - 3 Sept 1999
Externally published	Yes

Keywords

Ab initio calculations
Carbonyl complexes
Iron
Phosphinidene complexes
Phosphorus heterocycles

ASJC Scopus subject areas

Catalysis
General Chemistry

Access to Document

10.1002/(SICI)1521-3773(19990903)38:17<2596::AID-ANIE2596>3.0.CO;2-I

Cite this

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title = "Olefin cycloadditions of the electrophilic phosphinidene complex [iPr2N-P=Fe(CO)4]",

abstract = "Highly strained methylenephosphiranes are formed in the reaction of the new electrophilic phosphinidene complex [iPr2N-P = Fe(CO)4] with allenes. Remarkably, reaction with diallenes at 0 °C also leads to a phosphirane, which rearranges upon warming to room temperature to a bis- isopropylidenephospholene (see scheme).",

keywords = "Ab initio calculations, Carbonyl complexes, Iron, Phosphinidene complexes, Phosphorus heterocycles",

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year = "1999",

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T1 - Olefin cycloadditions of the electrophilic phosphinidene complex [iPr2N-P=Fe(CO)4]

AU - Wit, Jan B.M.

AU - Van Eijkel, Gerno T.

AU - De Kanter, Franciscus J.J.

AU - Schakel, Marius

AU - Ehlers, Andreas W.

AU - Lutz, Martin

AU - Spek, Anthony L.

AU - Lammertsma, Koop

PY - 1999/9/3

Y1 - 1999/9/3

N2 - Highly strained methylenephosphiranes are formed in the reaction of the new electrophilic phosphinidene complex [iPr2N-P = Fe(CO)4] with allenes. Remarkably, reaction with diallenes at 0 °C also leads to a phosphirane, which rearranges upon warming to room temperature to a bis- isopropylidenephospholene (see scheme).

AB - Highly strained methylenephosphiranes are formed in the reaction of the new electrophilic phosphinidene complex [iPr2N-P = Fe(CO)4] with allenes. Remarkably, reaction with diallenes at 0 °C also leads to a phosphirane, which rearranges upon warming to room temperature to a bis- isopropylidenephospholene (see scheme).

KW - Ab initio calculations

KW - Carbonyl complexes

KW - Iron

KW - Phosphinidene complexes

KW - Phosphorus heterocycles

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