Nucleophilic phosphinidene complexes: Access and applicability

Halil Aktaş; J. Chris Slootweg; Koop Lammertsma

doi:10.1002/anie.200905689

Nucleophilic phosphinidene complexes: Access and applicability

Halil Aktaş, J. Chris Slootweg, Koop Lammertsma

Vrije Universiteit Amsterdam

Research output: Contribution to journal › Review article › peer-review

200 Citations (Scopus)

Abstract

Syntheses, properties, and reactivities of nucleophilic phosphinidene complexes [L_nM=P-R] are reviewed. Emphasis is placed on the electronic tuning of this emerging class of phosphorus reagents, using different ancillary ligands and coordinatively unsaturated transitionmetal moieties. The difference in applicability of the established stable 18-electron and transient 16-electron phosphinidenes is addressed.

Original language	English
Pages (from-to)	2102-2113
Number of pages	12
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	12
DOIs	https://doi.org/10.1002/anie.200905689
Publication status	Published - 15 Mar 2010
Externally published	Yes

Keywords

Carbene homologues
Phosphinidene ligands
Phosphorus
Synthesis design
Transition metals

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.200905689

Cite this

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AB - Syntheses, properties, and reactivities of nucleophilic phosphinidene complexes [LnM=P-R] are reviewed. Emphasis is placed on the electronic tuning of this emerging class of phosphorus reagents, using different ancillary ligands and coordinatively unsaturated transitionmetal moieties. The difference in applicability of the established stable 18-electron and transient 16-electron phosphinidenes is addressed.

KW - Carbene homologues

KW - Phosphinidene ligands

KW - Phosphorus

KW - Synthesis design

KW - Transition metals

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Nucleophilic phosphinidene complexes: Access and applicability

Abstract

Keywords

ASJC Scopus subject areas

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