Nucleophilic or electrophilic phosphinidene complexes ML_n=PH; what makes the difference?

Chemistry

• Donor 100%
• Transition Element 50%
• Electrostatic Interaction 50%
• Density Functional Theory 50%
• Phosphorus Atom 50%
• Chemical Reactivity 50%
• Dissociation Energy 50%
• Bond Energy 50%
• Local-Density Approximation 50%
• Nucleophilicity 50%
• Electron Density 50%
• Coordination Compound 50%
• Transition Metals 50%

Keyphrases

• Nucleophilic 100%
• Charge Concentration 25%
• TiZr 25%
• High Affinity 25%
• Electron-rich 25%
• Nucleophilicity 25%
• Orbital Energy 25%