NTCDA-TTF first axial fusion: Emergent panchromatic, NIR optical, multi-state redox and high optical contrast photooxidation

Deepak Asthana, M. R. Ajayakumar, Rajendra Prasad Pant, Pritam Mukhopadhyay

Research output: Contribution to journalArticlepeer-review

23 Citations (Scopus)

Abstract

The first synthetic entry into axially fused NTCDA/PMDA-TTF multipolar molecules demonstrates a high optical contrast photooxidation, panchromism, low HOMO-LUMO gap, generation of a stable radical cation, NIR absorption/emission beyond 2150/800 nm and theoretically calculated NLO activity.

Original languageEnglish
Pages (from-to)6475-6477
Number of pages3
JournalChemical Communications
Volume48
Issue number52
DOIs
Publication statusPublished - 6 Jun 2012
Externally publishedYes

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Catalysis
  • Ceramics and Composites
  • General Chemistry
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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