NTCDA-TTF first axial fusion: Emergent panchromatic, NIR optical, multi-state redox and high optical contrast photooxidation

Deepak Asthana; M. R. Ajayakumar; Rajendra Prasad Pant; Pritam Mukhopadhyay

doi:10.1039/c2cc31274c

NTCDA-TTF first axial fusion: Emergent panchromatic, NIR optical, multi-state redox and high optical contrast photooxidation

Deepak Asthana, M. R. Ajayakumar, Rajendra Prasad Pant, Pritam Mukhopadhyay

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

The first synthetic entry into axially fused NTCDA/PMDA-TTF multipolar molecules demonstrates a high optical contrast photooxidation, panchromism, low HOMO-LUMO gap, generation of a stable radical cation, NIR absorption/emission beyond 2150/800 nm and theoretically calculated NLO activity.

Original language	English
Pages (from-to)	6475-6477
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	52
DOIs	https://doi.org/10.1039/c2cc31274c
Publication status	Published - 6 Jun 2012
Externally published	Yes

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c2cc31274c

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title = "NTCDA-TTF first axial fusion: Emergent panchromatic, NIR optical, multi-state redox and high optical contrast photooxidation",

abstract = "The first synthetic entry into axially fused NTCDA/PMDA-TTF multipolar molecules demonstrates a high optical contrast photooxidation, panchromism, low HOMO-LUMO gap, generation of a stable radical cation, NIR absorption/emission beyond 2150/800 nm and theoretically calculated NLO activity.",

author = "Deepak Asthana and Ajayakumar, {M. R.} and Pant, {Rajendra Prasad} and Pritam Mukhopadhyay",

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AU - Asthana, Deepak

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AU - Pant, Rajendra Prasad

AU - Mukhopadhyay, Pritam

PY - 2012/6/6

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AB - The first synthetic entry into axially fused NTCDA/PMDA-TTF multipolar molecules demonstrates a high optical contrast photooxidation, panchromism, low HOMO-LUMO gap, generation of a stable radical cation, NIR absorption/emission beyond 2150/800 nm and theoretically calculated NLO activity.

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NTCDA-TTF first axial fusion: Emergent panchromatic, NIR optical, multi-state redox and high optical contrast photooxidation

Abstract

ASJC Scopus subject areas

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