Novel approach to multimetal metallaborane clusters. Synthesis of hypoelectronic nido-Cp* 3IrRu 2B 5H 9 from the reaction of arachno-Cp*IrB 3K 9 with nido-(Cp*RuH) 2B 3H 7

Ipe J. Mavunkal; Bruce C. Noll; Reinout Meijboom; Alfred Muller; Thomas P. Fehlner

doi:10.1021/om060213i

Novel approach to multimetal metallaborane clusters. Synthesis of hypoelectronic nido-Cp* ₃IrRu ₂B ₅H ₉ from the reaction of arachno-CpIrB ₃K ₉ with nido-(CpRuH) ₂B ₃H ₇

Ipe J. Mavunkal, Bruce C. Noll, Reinout Meijboom, Alfred Muller, Thomas P. Fehlner

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

Two new mixed-metal metallaborane clusters, Cp* ₃-Ru ₂IrB ₅H ₉ and Cp* ₃Ru ₂IrB ₅H ₅, were isolated from the reaction of an iridaborane with a ruthenaborane. The structures show the former to have an unusual nido eight-atom cluster shape with a low electron count and the latter to have the expected bicapped-octahedral geometry.

Original language	English
Pages (from-to)	2906-2907
Number of pages	2
Journal	Organometallics
Volume	25
Issue number	12
DOIs	https://doi.org/10.1021/om060213i
Publication status	Published - 5 Jun 2006
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Access to Document

10.1021/om060213i

Cite this

@article{8af85a9a5e0d41919393505c1b5a2497,

title = "Novel approach to multimetal metallaborane clusters. Synthesis of hypoelectronic nido-Cp* 3IrRu 2B 5H 9 from the reaction of arachno-Cp*IrB 3K 9 with nido-(Cp*RuH) 2B 3H 7 ",

abstract = "Two new mixed-metal metallaborane clusters, Cp* 3-Ru 2IrB 5H 9 and Cp* 3Ru 2IrB 5H 5, were isolated from the reaction of an iridaborane with a ruthenaborane. The structures show the former to have an unusual nido eight-atom cluster shape with a low electron count and the latter to have the expected bicapped-octahedral geometry.",

author = "Mavunkal, {Ipe J.} and Noll, {Bruce C.} and Reinout Meijboom and Alfred Muller and Fehlner, {Thomas P.}",

year = "2006",

month = jun,

day = "5",

doi = "10.1021/om060213i",

language = "English",

volume = "25",

pages = "2906--2907",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "12",

}

TY - JOUR

T1 - Novel approach to multimetal metallaborane clusters. Synthesis of hypoelectronic nido-Cp* 3IrRu 2B 5H 9 from the reaction of arachno-Cp*IrB 3K 9 with nido-(Cp*RuH) 2B 3H 7

AU - Mavunkal, Ipe J.

AU - Noll, Bruce C.

AU - Meijboom, Reinout

AU - Muller, Alfred

AU - Fehlner, Thomas P.

PY - 2006/6/5

Y1 - 2006/6/5

N2 - Two new mixed-metal metallaborane clusters, Cp* 3-Ru 2IrB 5H 9 and Cp* 3Ru 2IrB 5H 5, were isolated from the reaction of an iridaborane with a ruthenaborane. The structures show the former to have an unusual nido eight-atom cluster shape with a low electron count and the latter to have the expected bicapped-octahedral geometry.

AB - Two new mixed-metal metallaborane clusters, Cp* 3-Ru 2IrB 5H 9 and Cp* 3Ru 2IrB 5H 5, were isolated from the reaction of an iridaborane with a ruthenaborane. The structures show the former to have an unusual nido eight-atom cluster shape with a low electron count and the latter to have the expected bicapped-octahedral geometry.

UR - http://www.scopus.com/inward/record.url?scp=33745796832&partnerID=8YFLogxK

U2 - 10.1021/om060213i

DO - 10.1021/om060213i

M3 - Article

AN - SCOPUS:33745796832

SN - 0276-7333

VL - 25

SP - 2906

EP - 2907

JO - Organometallics

JF - Organometallics

IS - 12

ER -

Novel approach to multimetal metallaborane clusters. Synthesis of hypoelectronic nido-Cp* ₃IrRu ₂B ₅H ₉ from the reaction of arachno-CpIrB ₃K ₉ with nido-(CpRuH) ₂B ₃H ₇

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this