Notes. Formation of carbonato and hydroxo complexes of vanadium(IV) on reaction of carbonylbis(η-pentamethylcyclopentadienyl)vanadium(II) with dinitrogen oxide

Frank Bottomley; James Darkwa

doi:10.1039/DT9880002505

Notes. Formation of carbonato and hydroxo complexes of vanadium(IV) on reaction of carbonylbis(η-pentamethylcyclopentadienyl)vanadium(II) with dinitrogen oxide

Frank Bottomley, James Darkwa

University of New Brunswick

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

The reaction between [V(η-C₅Me₅)₂(CO)] and N₂O in toluene at 20 °C gave a mixture of the vanadium(IV) carbonate [V(η-C₅Me₅)₂(CO₃)] and a polymer proposed to be [{[{V(η-C₅Me₅)-(μ-O)}₄(OH) ₂](μ-O)}_n]. The reaction is compared with analogous ones of [V(η-C₅H₅)₂(CO)] and [Ti(η-C₅R₅)₂(CO)₂] (R = H or Me).

Original language	English
Pages (from-to)	2505-2506
Number of pages	2
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	9
DOIs	https://doi.org/10.1039/DT9880002505
Publication status	Published - 1988
Externally published	Yes

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General Chemistry

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title = "Notes. Formation of carbonato and hydroxo complexes of vanadium(IV) on reaction of carbonylbis(η-pentamethylcyclopentadienyl)vanadium(II) with dinitrogen oxide",

abstract = "The reaction between [V(η-C5Me5)2(CO)] and N2O in toluene at 20 °C gave a mixture of the vanadium(IV) carbonate [V(η-C5Me5)2(CO3)] and a polymer proposed to be [{[{V(η-C5Me5)-(μ-O)}4(OH) 2](μ-O)}n]. The reaction is compared with analogous ones of [V(η-C5H5)2(CO)] and [Ti(η-C5R5)2(CO)2] (R = H or Me).",

author = "Frank Bottomley and James Darkwa",

year = "1988",

doi = "10.1039/DT9880002505",

language = "English",

pages = "2505--2506",

journal = "Journal of the Chemical Society. Dalton Transactions",

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publisher = "Royal Society of Chemistry",

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T1 - Notes. Formation of carbonato and hydroxo complexes of vanadium(IV) on reaction of carbonylbis(η-pentamethylcyclopentadienyl)vanadium(II) with dinitrogen oxide

AU - Bottomley, Frank

AU - Darkwa, James

PY - 1988

Y1 - 1988

N2 - The reaction between [V(η-C5Me5)2(CO)] and N2O in toluene at 20 °C gave a mixture of the vanadium(IV) carbonate [V(η-C5Me5)2(CO3)] and a polymer proposed to be [{[{V(η-C5Me5)-(μ-O)}4(OH) 2](μ-O)}n]. The reaction is compared with analogous ones of [V(η-C5H5)2(CO)] and [Ti(η-C5R5)2(CO)2] (R = H or Me).

AB - The reaction between [V(η-C5Me5)2(CO)] and N2O in toluene at 20 °C gave a mixture of the vanadium(IV) carbonate [V(η-C5Me5)2(CO3)] and a polymer proposed to be [{[{V(η-C5Me5)-(μ-O)}4(OH) 2](μ-O)}n]. The reaction is compared with analogous ones of [V(η-C5H5)2(CO)] and [Ti(η-C5R5)2(CO)2] (R = H or Me).

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DO - 10.1039/DT9880002505

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JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

IS - 9

ER -

Notes. Formation of carbonato and hydroxo complexes of vanadium(IV) on reaction of carbonylbis(η-pentamethylcyclopentadienyl)vanadium(II) with dinitrogen oxide

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