(Nitrito-κ2O,O′)bis­[tris­(4-methyl­phen­yl)phosphane-κP]silver(I)

Frederick P. Malan; Kariska Potgieter; Reinout Meijboom

doi:10.1107/S2414314622011488

(Nitrito-κ²O,O′)bis[tris(4-methylphenyl)phosphane-κP]silver(I)

Frederick P. Malan, Kariska Potgieter, Reinout Meijboom

Chemical Sciences

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The molecular structure of the title compound, [Ag(NO2)(C21H21P)2], exhibits a pseudo-Tetrahedral coordination around the central AgI atom. The compound crystallizes with one molecule in the asymmetric unit in the monoclinic space group P21/n with a rather long b axis [33.8752 (2) Å]. Weak C-H⋯O and C-H⋯N interactions consolidate the crystal packing. The nitrite-O atoms each occupy a single position in the coordination geometry.

Original language	English
Article number	x221148
Journal	IUCrData
Volume	7
DOIs	https://doi.org/10.1107/S2414314622011488
Publication status	Published - 6 Dec 2022

Keywords

crystal structure
p-Tolyl phosphine
silver(I) complex

ASJC Scopus subject areas

Analytical Chemistry
Inorganic Chemistry
Organic Chemistry

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10.1107/S2414314622011488

Cite this

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title = "(Nitrito-κ2O,O′)bis[tris(4-methylphenyl)phosphane-κP]silver(I)",

abstract = "The molecular structure of the title compound, [Ag(NO2)(C21H21P)2], exhibits a pseudo-Tetrahedral coordination around the central AgI atom. The compound crystallizes with one molecule in the asymmetric unit in the monoclinic space group P21/n with a rather long b axis [33.8752 (2) {\AA}]. Weak C-H⋯O and C-H⋯N interactions consolidate the crystal packing. The nitrite-O atoms each occupy a single position in the coordination geometry.",

keywords = "crystal structure, p-Tolyl phosphine, silver(I) complex",

author = "Malan, \{Frederick P.\} and Kariska Potgieter and Reinout Meijboom",

year = "2022",

month = dec,

day = "6",

doi = "10.1107/S2414314622011488",

language = "English",

volume = "7",

journal = "IUCrData",

issn = "2414-3146",

publisher = "International Union of Crystallography",

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TY - JOUR

T1 - (Nitrito-κ2O,O′)bis[tris(4-methylphenyl)phosphane-κP]silver(I)

AU - Malan, Frederick P.

AU - Potgieter, Kariska

AU - Meijboom, Reinout

PY - 2022/12/6

Y1 - 2022/12/6

N2 - The molecular structure of the title compound, [Ag(NO2)(C21H21P)2], exhibits a pseudo-Tetrahedral coordination around the central AgI atom. The compound crystallizes with one molecule in the asymmetric unit in the monoclinic space group P21/n with a rather long b axis [33.8752 (2) Å]. Weak C-H⋯O and C-H⋯N interactions consolidate the crystal packing. The nitrite-O atoms each occupy a single position in the coordination geometry.

AB - The molecular structure of the title compound, [Ag(NO2)(C21H21P)2], exhibits a pseudo-Tetrahedral coordination around the central AgI atom. The compound crystallizes with one molecule in the asymmetric unit in the monoclinic space group P21/n with a rather long b axis [33.8752 (2) Å]. Weak C-H⋯O and C-H⋯N interactions consolidate the crystal packing. The nitrite-O atoms each occupy a single position in the coordination geometry.

KW - crystal structure

KW - p-Tolyl phosphine

KW - silver(I) complex

UR - https://www.scopus.com/pages/publications/85149380576

U2 - 10.1107/S2414314622011488

DO - 10.1107/S2414314622011488

M3 - Article

AN - SCOPUS:85149380576

SN - 2414-3146

VL - 7

JO - IUCrData

JF - IUCrData

M1 - x221148

ER -

(Nitrito-κ²O,O′)bis[tris(4-methylphenyl)phosphane-κP]silver(I)

Abstract

Keywords

ASJC Scopus subject areas

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Cite this

(Nitrito-κ2O,O′)bis­[tris­(4-methyl­phen­yl)phosphane-κP]silver(I)

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

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Fingerprint

Cite this

(Nitrito-κ²O,O′)bis[tris(4-methylphenyl)phosphane-κP]silver(I)