(Nitrito-κ2O,O′)bis­[tris­(4-methyl­phen­yl)phosphane-κP]silver(I)

Frederick P. Malan, Kariska Potgieter, Reinout Meijboom

Research output: Contribution to journalArticlepeer-review

Abstract

The mol­ecular structure of the title compound, [Ag(NO2)(C21H21P)2], exhibits a pseudo-Tetra­hedral coordination around the central AgI atom. The compound crystallizes with one mol­ecule in the asymmetric unit in the monoclinic space group P21/n with a rather long b axis [33.8752 (2) Å]. Weak C-H⋯O and C-H⋯N inter­actions consolidate the crystal packing. The nitrite-O atoms each occupy a single position in the coordination geometry.

Original languageEnglish
Article numberx221148
JournalIUCrData
Volume7
DOIs
Publication statusPublished - 6 Dec 2022

Keywords

  • crystal structure
  • p-Tolyl phosphine
  • silver(I) complex

ASJC Scopus subject areas

  • Analytical Chemistry
  • Inorganic Chemistry
  • Organic Chemistry

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