Neutral palladium(II) complexes with P,N Schiff-base ligands: Synthesis, characterization and application as Suzuki-Miyaura coupling catalysts

Tebello Mahamo; Mokgolela M. Mogorosi; John R. Moss; Selwyn F. Mapolie; J. Chris Slootweg; Koop Lammertsma; Gregory S. Smith

doi:10.1016/j.jorganchem.2011.12.021

Neutral palladium(II) complexes with P,N Schiff-base ligands: Synthesis, characterization and application as Suzuki-Miyaura coupling catalysts

Tebello Mahamo, Mokgolela M. Mogorosi, John R. Moss, Selwyn F. Mapolie, J. Chris Slootweg, Koop Lammertsma, Gregory S. Smith

Research output: Contribution to journal › Article › peer-review

51 Citations (Scopus)

Abstract

Palladium(II) complexes of the general formulae [PdCl ₂(PN)] and [Pd(Me)Cl(PN)] were obtained from bidentate ligands bearing phosphine and imine donor groups. The complexes were shown to be highly active catalysts for the Suzuki-Miyaura cross-coupling reaction. The complexes are tolerant of a wide variety of reaction conditions such as solvent, choice of base as well as substituents on both arylboronic acids and aryl halides.

Original language	English
Pages (from-to)	34-42
Number of pages	9
Journal	Journal of Organometallic Chemistry
Volume	703
DOIs	https://doi.org/10.1016/j.jorganchem.2011.12.021
Publication status	Published - 15 Apr 2012
Externally published	Yes

Keywords

Aryl halides
Arylboronic acids
Iminophosphines
Palladium(II) complexes
Suzuki-Miyaura coupling

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/j.jorganchem.2011.12.021

Cite this

@article{9649e13adb0c4c95bd9cbe09337adbc3,

title = "Neutral palladium(II) complexes with P,N Schiff-base ligands: Synthesis, characterization and application as Suzuki-Miyaura coupling catalysts",

abstract = "Palladium(II) complexes of the general formulae [PdCl 2(PN)] and [Pd(Me)Cl(PN)] were obtained from bidentate ligands bearing phosphine and imine donor groups. The complexes were shown to be highly active catalysts for the Suzuki-Miyaura cross-coupling reaction. The complexes are tolerant of a wide variety of reaction conditions such as solvent, choice of base as well as substituents on both arylboronic acids and aryl halides.",

keywords = "Aryl halides, Arylboronic acids, Iminophosphines, Palladium(II) complexes, Suzuki-Miyaura coupling",

author = "Tebello Mahamo and Mogorosi, {Mokgolela M.} and Moss, {John R.} and Mapolie, {Selwyn F.} and {Chris Slootweg}, J. and Koop Lammertsma and Smith, {Gregory S.}",

year = "2012",

month = apr,

day = "15",

doi = "10.1016/j.jorganchem.2011.12.021",

language = "English",

volume = "703",

pages = "34--42",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Neutral palladium(II) complexes with P,N Schiff-base ligands

T2 - Synthesis, characterization and application as Suzuki-Miyaura coupling catalysts

AU - Mahamo, Tebello

AU - Mogorosi, Mokgolela M.

AU - Moss, John R.

AU - Mapolie, Selwyn F.

AU - Chris Slootweg, J.

AU - Lammertsma, Koop

AU - Smith, Gregory S.

PY - 2012/4/15

Y1 - 2012/4/15

N2 - Palladium(II) complexes of the general formulae [PdCl 2(PN)] and [Pd(Me)Cl(PN)] were obtained from bidentate ligands bearing phosphine and imine donor groups. The complexes were shown to be highly active catalysts for the Suzuki-Miyaura cross-coupling reaction. The complexes are tolerant of a wide variety of reaction conditions such as solvent, choice of base as well as substituents on both arylboronic acids and aryl halides.

AB - Palladium(II) complexes of the general formulae [PdCl 2(PN)] and [Pd(Me)Cl(PN)] were obtained from bidentate ligands bearing phosphine and imine donor groups. The complexes were shown to be highly active catalysts for the Suzuki-Miyaura cross-coupling reaction. The complexes are tolerant of a wide variety of reaction conditions such as solvent, choice of base as well as substituents on both arylboronic acids and aryl halides.

KW - Aryl halides

KW - Arylboronic acids

KW - Iminophosphines

KW - Palladium(II) complexes

KW - Suzuki-Miyaura coupling

UR - http://www.scopus.com/inward/record.url?scp=84862823845&partnerID=8YFLogxK

U2 - 10.1016/j.jorganchem.2011.12.021

DO - 10.1016/j.jorganchem.2011.12.021

M3 - Article

AN - SCOPUS:84862823845

SN - 0022-328X

VL - 703

SP - 34

EP - 42

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -

Neutral palladium(II) complexes with P,N Schiff-base ligands: Synthesis, characterization and application as Suzuki-Miyaura coupling catalysts

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this