Abstract
This study reports column flow adsorption capacity for Pb and Cu of 56.54 mgg -1 and 5.75 mgg -1, respectively, using electrospun nanofibers (70-264 nm) of chitosan:polyacrylamide blend ratio 77:23 with glutaraldehyde cross-linking. The Freundlich isotherms gave a better fit than Langmuir. The fibers were applied in contaminated pond water and pulp wastewater, for removal of Pb and Cu, with removal efficiencies of 100% (Pb) and 98.6% (Cu) in pond water; and 97.2% (Pb) and 99.5% (Cu) in wastewater. The regeneration efficiencies (recovery %) were 64% (Pb) and 89% (Cu) in pond; 72% (Pb) and 90% (Cu) for pulp, respectively, using an adsorbent mass of 0.05g.
Original language | English |
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Pages (from-to) | 1937-1955 |
Number of pages | 19 |
Journal | Analytical Letters |
Volume | 44 |
Issue number | 11 |
DOIs | |
Publication status | Published - Jul 2011 |
Keywords
- Adsorption kinetics
- Chitosan-polyacrylamide blend
- Electrospinning
- Heavy metal removal
- Nanofibers
- Wastewater
ASJC Scopus subject areas
- Analytical Chemistry
- Biochemistry
- Spectroscopy
- Clinical Biochemistry
- Biochemistry (medical)
- Electrochemistry