Mössbauer spectroscopy of exchangeable ions

A. Mulaba-Bafubiandi; J. A. Helsen; R. Paterson; G. Langouche

doi:10.1007/BF02405498

Mössbauer spectroscopy of exchangeable ions

A. Mulaba-Bafubiandi, J. A. Helsen, R. Paterson, G. Langouche

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

In this paper Mössbauer spectroscopy is used to study anion exchange processes. In β-FeOOH the effect of the exchangeable ions OH^-, Cl^- and F^- on lattice iron is studied. For the anion exchangers ZrO₂ and the resins amberlite IRA 400, Dowex MSA-1 and Dowex MWA-1, Fe(II)- and Fe(III) hexacyanides are used as Mössbauer probes. The confirmation of a third doublet in F^--exchanged β-FeOOH and the perturbation of redox equilibrium in the other exchangers are the main observations.

Original language	English
Pages (from-to)	1701-1706
Number of pages	6
Journal	Hyperfine Interactions
Volume	56
Issue number	1-4
DOIs	https://doi.org/10.1007/BF02405498
Publication status	Published - Jul 1990
Externally published	Yes

ASJC Scopus subject areas

Atomic and Molecular Physics, and Optics
Nuclear and High Energy Physics
Condensed Matter Physics
Physical and Theoretical Chemistry

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10.1007/BF02405498

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title = "M{\"o}ssbauer spectroscopy of exchangeable ions",

abstract = "In this paper M{\"o}ssbauer spectroscopy is used to study anion exchange processes. In β-FeOOH the effect of the exchangeable ions OH-, Cl- and F- on lattice iron is studied. For the anion exchangers ZrO2 and the resins amberlite IRA 400, Dowex MSA-1 and Dowex MWA-1, Fe(II)- and Fe(III) hexacyanides are used as M{\"o}ssbauer probes. The confirmation of a third doublet in F--exchanged β-FeOOH and the perturbation of redox equilibrium in the other exchangers are the main observations.",

author = "A. Mulaba-Bafubiandi and Helsen, {J. A.} and R. Paterson and G. Langouche",

year = "1990",

month = jul,

doi = "10.1007/BF02405498",

language = "English",

volume = "56",

pages = "1701--1706",

journal = "Hyperfine Interactions",

issn = "0304-3843",

publisher = "Springer Nature",

number = "1-4",

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TY - JOUR

T1 - Mössbauer spectroscopy of exchangeable ions

AU - Mulaba-Bafubiandi, A.

AU - Helsen, J. A.

AU - Paterson, R.

AU - Langouche, G.

PY - 1990/7

Y1 - 1990/7

N2 - In this paper Mössbauer spectroscopy is used to study anion exchange processes. In β-FeOOH the effect of the exchangeable ions OH-, Cl- and F- on lattice iron is studied. For the anion exchangers ZrO2 and the resins amberlite IRA 400, Dowex MSA-1 and Dowex MWA-1, Fe(II)- and Fe(III) hexacyanides are used as Mössbauer probes. The confirmation of a third doublet in F--exchanged β-FeOOH and the perturbation of redox equilibrium in the other exchangers are the main observations.

AB - In this paper Mössbauer spectroscopy is used to study anion exchange processes. In β-FeOOH the effect of the exchangeable ions OH-, Cl- and F- on lattice iron is studied. For the anion exchangers ZrO2 and the resins amberlite IRA 400, Dowex MSA-1 and Dowex MWA-1, Fe(II)- and Fe(III) hexacyanides are used as Mössbauer probes. The confirmation of a third doublet in F--exchanged β-FeOOH and the perturbation of redox equilibrium in the other exchangers are the main observations.

UR - http://www.scopus.com/inward/record.url?scp=0342606166&partnerID=8YFLogxK

U2 - 10.1007/BF02405498

DO - 10.1007/BF02405498

M3 - Article

AN - SCOPUS:0342606166

SN - 0304-3843

VL - 56

SP - 1701

EP - 1706

JO - Hyperfine Interactions

JF - Hyperfine Interactions

IS - 1-4

ER -

Mössbauer spectroscopy of exchangeable ions

Abstract

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