TY - JOUR
T1 - Kinetics of simultaneous degradation of brilliant green and methyl orange using biosynthesized high functional Ag nanoparticles
AU - Ali, Faisal
AU - Safdar, Anosha
AU - Younas, Umer
AU - Sillanpaa, Mika
AU - Pervaiz, Muhammad
AU - Nazir, Arif
AU - Naeem, Muhammad
AU - Iqbal, Munawar
AU - Al-Kahtani, Abdullah A.
AU - Tighezza, Ammar Mohamed
N1 - Publisher Copyright:
© 2023 Walter de Gruyter GmbH, Berlin/Boston.
PY - 2023/4/1
Y1 - 2023/4/1
N2 - Nanoparticles synthesised using natural resources is a cost-effective and ecofriendly technique with a number of advantages. In current work, silver nanoparticles (AgNPs) have been synthesized using the extract of Fragaria ananassa seeds. The extract was used as a source of phytochemicals that can act as reducing and stabilizing agents. The characteristics of AgNPs were determined by UV/Visible, FTIR, SEM, XRD and Dynamic light scattering (DLS) techniques. The appearance of the distinctive absorption peak in UV-visible spectra at 430 nm confirmed the formation of AgNPs. The involvement of different bioactive functional groups with AgNPs was authenticated by FTIR studies. Particle size and morphology was confirmed by DLS, SEM and XRD analysis. The catalytic potential of AgNPs for the removal of poisonous organic dyes, brilliant green (BG) and methyl orange (MO) was also tested. Effect of different parameters including the catalyst concentration, dyes concentration and presence of different salts on the degradation of dyes was investigated. Nano-size and well-distributed nature of AgNPs, BG and MO dyes were degraded rapidly individually as well as simultaneously. The degradation process obeyed pseudo first order kinetics. Authors concluded that AgNPs synthesized using environment friendly and cost-effective method, can be used as a new tool to combat pollution caused by carcinogenic organic dyes.
AB - Nanoparticles synthesised using natural resources is a cost-effective and ecofriendly technique with a number of advantages. In current work, silver nanoparticles (AgNPs) have been synthesized using the extract of Fragaria ananassa seeds. The extract was used as a source of phytochemicals that can act as reducing and stabilizing agents. The characteristics of AgNPs were determined by UV/Visible, FTIR, SEM, XRD and Dynamic light scattering (DLS) techniques. The appearance of the distinctive absorption peak in UV-visible spectra at 430 nm confirmed the formation of AgNPs. The involvement of different bioactive functional groups with AgNPs was authenticated by FTIR studies. Particle size and morphology was confirmed by DLS, SEM and XRD analysis. The catalytic potential of AgNPs for the removal of poisonous organic dyes, brilliant green (BG) and methyl orange (MO) was also tested. Effect of different parameters including the catalyst concentration, dyes concentration and presence of different salts on the degradation of dyes was investigated. Nano-size and well-distributed nature of AgNPs, BG and MO dyes were degraded rapidly individually as well as simultaneously. The degradation process obeyed pseudo first order kinetics. Authors concluded that AgNPs synthesized using environment friendly and cost-effective method, can be used as a new tool to combat pollution caused by carcinogenic organic dyes.
KW - catalysis
KW - green synthesis
KW - kinetics
KW - silver nanoparticles
KW - simultaneous degradation
UR - http://www.scopus.com/inward/record.url?scp=85154615433&partnerID=8YFLogxK
U2 - 10.1515/zpch-2022-0098
DO - 10.1515/zpch-2022-0098
M3 - Article
AN - SCOPUS:85154615433
SN - 0942-9352
VL - 237
SP - 599
EP - 616
JO - Zeitschrift fur Physikalische Chemie
JF - Zeitschrift fur Physikalische Chemie
IS - 4-5
ER -