Kinetic studies on the transport behavior of hybrid filler incorporated natural rubber (NR)

Vakkoottil Sivadasan Abhisha; Krishanagegham Sidharathan Sisanth; Sabu Thomas; Ranimol Stephen

doi:10.3144/expresspolymlett.2023.80

Kinetic studies on the transport behavior of hybrid filler incorporated natural rubber (NR)

Vakkoottil Sivadasan Abhisha, Krishanagegham Sidharathan Sisanth, Sabu Thomas, Ranimol Stephen

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Conductive carbon black (CCB), carbon nanotubes (CNT) and its hybrids are introduced into the natural rubber (NR) matrix aiming to explore the effect of filler ratio on the transport properties. Solvent transport of NR is found to decrease for hybrid filler systems as compared to single filler incorporated systems. Kinetic parameters of solvent transport behavior of filled NR systems are analyzed using various kinetic models. Upon the computation of kinetic parameters of transport data, it is found that the Peppas-Sahlin model is in good agreement with experimental observations, which suggests that the transport mechanism is diffusion controlled. Rubber–filler interaction parameters are computed and analyzed from the swelling experiments using Kraus, Cunneen-Russel, and Lorenz-Park equations.

Original language	English
Pages (from-to)	1070-1080
Number of pages	11
Journal	Express Polymer Letters
Volume	17
Issue number	10
DOIs	https://doi.org/10.3144/expresspolymlett.2023.80
Publication status	Published - Oct 2023
Externally published	Yes

Keywords

carbon black
crosslinking
curing
elastomer
filler
natural rubber
transport properties
vulcanization

ASJC Scopus subject areas

General Chemical Engineering
Physical and Theoretical Chemistry
Polymers and Plastics
Organic Chemistry
Materials Chemistry

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10.3144/expresspolymlett.2023.80

Cite this

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title = "Kinetic studies on the transport behavior of hybrid filler incorporated natural rubber (NR)",

abstract = "Conductive carbon black (CCB), carbon nanotubes (CNT) and its hybrids are introduced into the natural rubber (NR) matrix aiming to explore the effect of filler ratio on the transport properties. Solvent transport of NR is found to decrease for hybrid filler systems as compared to single filler incorporated systems. Kinetic parameters of solvent transport behavior of filled NR systems are analyzed using various kinetic models. Upon the computation of kinetic parameters of transport data, it is found that the Peppas-Sahlin model is in good agreement with experimental observations, which suggests that the transport mechanism is diffusion controlled. Rubber–filler interaction parameters are computed and analyzed from the swelling experiments using Kraus, Cunneen-Russel, and Lorenz-Park equations.",

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author = "Abhisha, \{Vakkoottil Sivadasan\} and Sisanth, \{Krishanagegham Sidharathan\} and Sabu Thomas and Ranimol Stephen",

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TY - JOUR

T1 - Kinetic studies on the transport behavior of hybrid filler incorporated natural rubber (NR)

AU - Abhisha, Vakkoottil Sivadasan

AU - Sisanth, Krishanagegham Sidharathan

AU - Thomas, Sabu

AU - Stephen, Ranimol

N1 - Publisher Copyright: © BME-PT.

PY - 2023/10

Y1 - 2023/10

N2 - Conductive carbon black (CCB), carbon nanotubes (CNT) and its hybrids are introduced into the natural rubber (NR) matrix aiming to explore the effect of filler ratio on the transport properties. Solvent transport of NR is found to decrease for hybrid filler systems as compared to single filler incorporated systems. Kinetic parameters of solvent transport behavior of filled NR systems are analyzed using various kinetic models. Upon the computation of kinetic parameters of transport data, it is found that the Peppas-Sahlin model is in good agreement with experimental observations, which suggests that the transport mechanism is diffusion controlled. Rubber–filler interaction parameters are computed and analyzed from the swelling experiments using Kraus, Cunneen-Russel, and Lorenz-Park equations.

AB - Conductive carbon black (CCB), carbon nanotubes (CNT) and its hybrids are introduced into the natural rubber (NR) matrix aiming to explore the effect of filler ratio on the transport properties. Solvent transport of NR is found to decrease for hybrid filler systems as compared to single filler incorporated systems. Kinetic parameters of solvent transport behavior of filled NR systems are analyzed using various kinetic models. Upon the computation of kinetic parameters of transport data, it is found that the Peppas-Sahlin model is in good agreement with experimental observations, which suggests that the transport mechanism is diffusion controlled. Rubber–filler interaction parameters are computed and analyzed from the swelling experiments using Kraus, Cunneen-Russel, and Lorenz-Park equations.

KW - carbon black

KW - crosslinking

KW - curing

KW - elastomer

KW - filler

KW - natural rubber

KW - transport properties

KW - vulcanization

UR - https://www.scopus.com/pages/publications/85168237803

U2 - 10.3144/expresspolymlett.2023.80

DO - 10.3144/expresspolymlett.2023.80

M3 - Article

AN - SCOPUS:85168237803

SN - 1788-618X

VL - 17

SP - 1070

EP - 1080

JO - Express Polymer Letters

JF - Express Polymer Letters

IS - 10

ER -

Kinetic studies on the transport behavior of hybrid filler incorporated natural rubber (NR)

Abstract

Keywords

ASJC Scopus subject areas

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