Isothermal vapor-liquid equilibrium data and thermodynamic modeling for binary systems of perfluorobutane (R610) + (methane or hydrogen sulfide) at (293, 313, and 333) K

Mulamba Marc Tshibangu; Alain Valtz; Caleb Narasigadu; Christophe Coquelet; Deresh Ramjugernath

doi:10.1021/je500496y

Isothermal vapor-liquid equilibrium data and thermodynamic modeling for binary systems of perfluorobutane (R610) + (methane or hydrogen sulfide) at (293, 313, and 333) K

Mulamba Marc Tshibangu, Alain Valtz, Caleb Narasigadu, Christophe Coquelet, Deresh Ramjugernath

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Isothermal vapor-liquid equilibrium data for binary systems comprising perfluorobutane (R610) with methane (CH₄) or hydrogen sulfide (H₂S) were measured at isothermal conditions of approximately (293, 313, and 333) K, and pressures up to 9.837 MPa. The data were measured using a ”static-analytic” apparatus equipped with a mobile pneumatic capillary sampler. The experimental data were correlated via the direct method using two sets of thermodynamic models. The Peng-Robinson equation of state incorporating the Mathias-Copeman α function, with the Wong-Sandler mixing rule utilizing the nonrandom two-liquid activity coefficient model, was used for the correlation of the CH₄ + C₄F₁₀ system, while the Soave-Redlich-Kwong equation of state incorporating the Mathias-Copeman α function, with the modified Huron-Vidal first-order mixing rule utilizing the nonrandom two-liquid activity coefficient model was used for the H₂S + C₄F₁₀ system.

Original language	English
Pages (from-to)	2866-2871
Number of pages	6
Journal	Journal of Chemical & Engineering Data
Volume	59
Issue number	9
DOIs	https://doi.org/10.1021/je500496y
Publication status	Published - 11 Sept 2014
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

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10.1021/je500496y

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title = "Isothermal vapor-liquid equilibrium data and thermodynamic modeling for binary systems of perfluorobutane (R610) + (methane or hydrogen sulfide) at (293, 313, and 333) K",

abstract = "Isothermal vapor-liquid equilibrium data for binary systems comprising perfluorobutane (R610) with methane (CH4) or hydrogen sulfide (H2S) were measured at isothermal conditions of approximately (293, 313, and 333) K, and pressures up to 9.837 MPa. The data were measured using a ”static-analytic” apparatus equipped with a mobile pneumatic capillary sampler. The experimental data were correlated via the direct method using two sets of thermodynamic models. The Peng-Robinson equation of state incorporating the Mathias-Copeman α function, with the Wong-Sandler mixing rule utilizing the nonrandom two-liquid activity coefficient model, was used for the correlation of the CH4 + C4F10 system, while the Soave-Redlich-Kwong equation of state incorporating the Mathias-Copeman α function, with the modified Huron-Vidal first-order mixing rule utilizing the nonrandom two-liquid activity coefficient model was used for the H2S + C4F10 system.",

author = "Tshibangu, {Mulamba Marc} and Alain Valtz and Caleb Narasigadu and Christophe Coquelet and Deresh Ramjugernath",

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Isothermal vapor-liquid equilibrium data and thermodynamic modeling for binary systems of perfluorobutane (R610) + (methane or hydrogen sulfide) at (293, 313, and 333) K. / Tshibangu, Mulamba Marc; Valtz, Alain; Narasigadu, Caleb et al.
In: Journal of Chemical & Engineering Data, Vol. 59, No. 9, 11.09.2014, p. 2866-2871.

Research output: Contribution to journal › Article › peer-review

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AU - Tshibangu, Mulamba Marc

AU - Valtz, Alain

AU - Narasigadu, Caleb

AU - Coquelet, Christophe

AU - Ramjugernath, Deresh

PY - 2014/9/11

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Isothermal vapor-liquid equilibrium data and thermodynamic modeling for binary systems of perfluorobutane (R610) + (methane or hydrogen sulfide) at (293, 313, and 333) K

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