Abstract
Novel dichlorobis(β-diketonato)titanium(IV) Ti(C6H5COCHCOR)2Cl2 and (2,2′-biphenyldiolato)bis(β-diketonato)titanium(IV) Ti(C6H5COCHCOR)2biphen complexes with R = CH3, C6H5 and CF3, are synthesized and characterized by X-ray crystallography and further physical methods. There is a good agreement between DFT calculated and experimental structural data. A configurational analysis gives a calculated isomer distribution that is in agreement with the experimental data derived from low temperature 1H NMR spectroscopy. The Ti(C6H5COCHCOR)2biphen complexes exhibit high hydrolytic stability.
Original language | English |
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Pages (from-to) | 3088-3096 |
Number of pages | 9 |
Journal | Inorganica Chimica Acta |
Volume | 362 |
Issue number | 9 |
DOIs | |
Publication status | Published - 1 Jul 2009 |
Externally published | Yes |
Keywords
- DFT
- Isomer distribution
- Structure
- Titanium
- β-Diketonato
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry