Iron in reduced charge montmorillonites

A. Mulaba-Bafubiandi; J. Helsen; A. Maes; G. Langouche

doi:10.1007/BF02397509

Iron in reduced charge montmorillonites

A. Mulaba-Bafubiandi, J. Helsen, A. Maes, G. Langouche

KU Leuven

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Reduced charge Camp-Berteau Montmorillonites (R.C.M.) have been studied. The Cation Exchange Capacity (C.E.C.) resulting from these samples with different Li/Na ratios decreased linearly from the original value of about 1 meq/g to 0.6 meq/g. Diffused Li⁺ ended in octahedral layer nearby Mg²⁺. Iron was as Fe³⁺ and mainly in octahedral sites. A small additional quantity of tetrahedral configuration was detected. Only minor modifications on Mössbauer parameters of R.C.M. samples were observed as a consequence of charge reduction.

Original language	English
Pages (from-to)	1049-1052
Number of pages	4
Journal	Hyperfine Interactions
Volume	70
Issue number	1-4
DOIs	https://doi.org/10.1007/BF02397509
Publication status	Published - Apr 1992
Externally published	Yes

ASJC Scopus subject areas

Atomic and Molecular Physics, and Optics
Nuclear and High Energy Physics
Condensed Matter Physics
Physical and Theoretical Chemistry

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10.1007/BF02397509

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abstract = "Reduced charge Camp-Berteau Montmorillonites (R.C.M.) have been studied. The Cation Exchange Capacity (C.E.C.) resulting from these samples with different Li/Na ratios decreased linearly from the original value of about 1 meq/g to 0.6 meq/g. Diffused Li+ ended in octahedral layer nearby Mg2+. Iron was as Fe3+ and mainly in octahedral sites. A small additional quantity of tetrahedral configuration was detected. Only minor modifications on M{\"o}ssbauer parameters of R.C.M. samples were observed as a consequence of charge reduction.",

author = "A. Mulaba-Bafubiandi and J. Helsen and A. Maes and G. Langouche",

year = "1992",

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doi = "10.1007/BF02397509",

language = "English",

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pages = "1049--1052",

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T1 - Iron in reduced charge montmorillonites

AU - Mulaba-Bafubiandi, A.

AU - Helsen, J.

AU - Maes, A.

AU - Langouche, G.

PY - 1992/4

Y1 - 1992/4

N2 - Reduced charge Camp-Berteau Montmorillonites (R.C.M.) have been studied. The Cation Exchange Capacity (C.E.C.) resulting from these samples with different Li/Na ratios decreased linearly from the original value of about 1 meq/g to 0.6 meq/g. Diffused Li+ ended in octahedral layer nearby Mg2+. Iron was as Fe3+ and mainly in octahedral sites. A small additional quantity of tetrahedral configuration was detected. Only minor modifications on Mössbauer parameters of R.C.M. samples were observed as a consequence of charge reduction.

AB - Reduced charge Camp-Berteau Montmorillonites (R.C.M.) have been studied. The Cation Exchange Capacity (C.E.C.) resulting from these samples with different Li/Na ratios decreased linearly from the original value of about 1 meq/g to 0.6 meq/g. Diffused Li+ ended in octahedral layer nearby Mg2+. Iron was as Fe3+ and mainly in octahedral sites. A small additional quantity of tetrahedral configuration was detected. Only minor modifications on Mössbauer parameters of R.C.M. samples were observed as a consequence of charge reduction.

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DO - 10.1007/BF02397509

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AN - SCOPUS:0004937282

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SP - 1049

EP - 1052

JO - Hyperfine Interactions

JF - Hyperfine Interactions

IS - 1-4

ER -

Iron in reduced charge montmorillonites

Abstract

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