Ionic liquid assisted extraction induced by emulsion breaking for extraction of trace metals in diesel, gasoline and kerosene prior to ICP-OES analysis

This study describes a novel and greener ionic liquid assisted extraction induced by emulsion breaking (ILA-EIEB) method for extraction of As, Ba, Cd, Cr, Ni Pb, Sb, Sn, Tb, Te and V in fuel oils. The most influential extraction parameters were ionic liquid concentration [(1-Ethyl-3-methylimidazolium bis (trifluoromethylsulfonyl)], HNO₃ concentration, Triton X-100 concentration, and sample mass and were optimised by using full factorial and Box-Behnken designs. The optimum conditions obtained were 0.035 % 1-Ethyl-3-methylimidazolium bis (trifluoromethylsulfonyl) concentration, 18 % v/v HNO₃ concentration, 15 % w/v Triton X-100 concentration, and 0.1 g sample mass. The emulsions were fully broken by using a controlled heating water bath at temperature of 80 ± 2 °C for 30 ± 4 min, followed by centrifugation at 3500 rpm for 15 min. Under the optimum conditions, the proposed ILA-EIEB method was accurate (80.1–101 %) and precise (1.9–4.7 %) for all the investigated metals. The method detection limits were 0.107, 0.013, 3.494 and 0.560 μg/g for Ba, Na, Ni and V, respectively. The optimised ILA-EIEB method was then applied in real fuel samples and metal concentration levels ranged from 0.072 to 8.610 μg/g, which were consistent with other literature reported work. Therefore, this study suggests that the examined metal ions present in fuel oils commercialised in Johannesburg, South Africa are in tolerable concentration levels and are not a threat.