Interactions of sulphur anions and stainless steels at kraft pulp digesting temperature

J. Rämö; M. Sillanpää; A. Kujala; O. Hyökyvirta; S. Peltonen

doi:10.1002/1521-4176(200107)52:7<531::aid-maco531>3.0.co;2-s

Interactions of sulphur anions and stainless steels at kraft pulp digesting temperature

J. Rämö, M. Sillanpää, A. Kujala, O. Hyökyvirta, S. Peltonen

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

Interactions of certain stainless steels (S30400, S31600, S31803, S32304) and sulphur anions, separately and in combination, at concentrations typical of kraft liquors were investigated using XRF and CER techniques. IC, ISE and ABC titration were applied in the modelling of behaviour of the sulphur anions. Nickel and sulphur enriched to the steel surfaces in all experiments. Abilities of molybdenum and chromium to remain in the surfaces appeared to be better than those of iron. Adhesion of sulphur onto austenitic grades was probably stronger than that of the duplex grades. Sulphide and combination of sulphur anions formed durable films, but films formed by thiosulphate possessed some gliding properties. For the solution, real amount of the sulphide was less than the added amount. Thiosulphate had a tendency to convert into sulphite.

Original language	English
Pages (from-to)	531-539
Number of pages	9
Journal	Materials and Corrosion - Werkstoffe und Korrosion
Volume	52
Issue number	7
DOIs	https://doi.org/10.1002/1521-4176(200107)52:7<531::aid-maco531>3.0.co;2-s
Publication status	Published - 2001
Externally published	Yes

ASJC Scopus subject areas

Environmental Chemistry
Mechanics of Materials
Mechanical Engineering
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1002/1521-4176(200107)52:7<531::aid-maco531>3.0.co;2-s

Cite this

@article{e8dd100d55fd4078a2b7f3064b13025f,

title = "Interactions of sulphur anions and stainless steels at kraft pulp digesting temperature",

abstract = "Interactions of certain stainless steels (S30400, S31600, S31803, S32304) and sulphur anions, separately and in combination, at concentrations typical of kraft liquors were investigated using XRF and CER techniques. IC, ISE and ABC titration were applied in the modelling of behaviour of the sulphur anions. Nickel and sulphur enriched to the steel surfaces in all experiments. Abilities of molybdenum and chromium to remain in the surfaces appeared to be better than those of iron. Adhesion of sulphur onto austenitic grades was probably stronger than that of the duplex grades. Sulphide and combination of sulphur anions formed durable films, but films formed by thiosulphate possessed some gliding properties. For the solution, real amount of the sulphide was less than the added amount. Thiosulphate had a tendency to convert into sulphite.",

author = "J. R{\"a}m{\"o} and M. Sillanp{\"a}{\"a} and A. Kujala and O. Hy{\"o}kyvirta and S. Peltonen",

year = "2001",

doi = "10.1002/1521-4176(200107)52:7<531::aid-maco531>3.0.co;2-s",

language = "English",

volume = "52",

pages = "531--539",

journal = "Materials and Corrosion - Werkstoffe und Korrosion",

issn = "0043-2822",

publisher = "John Wiley and Sons Ltd",

number = "7",

}

TY - JOUR

T1 - Interactions of sulphur anions and stainless steels at kraft pulp digesting temperature

AU - Rämö, J.

AU - Sillanpää, M.

AU - Kujala, A.

AU - Hyökyvirta, O.

AU - Peltonen, S.

PY - 2001

Y1 - 2001

N2 - Interactions of certain stainless steels (S30400, S31600, S31803, S32304) and sulphur anions, separately and in combination, at concentrations typical of kraft liquors were investigated using XRF and CER techniques. IC, ISE and ABC titration were applied in the modelling of behaviour of the sulphur anions. Nickel and sulphur enriched to the steel surfaces in all experiments. Abilities of molybdenum and chromium to remain in the surfaces appeared to be better than those of iron. Adhesion of sulphur onto austenitic grades was probably stronger than that of the duplex grades. Sulphide and combination of sulphur anions formed durable films, but films formed by thiosulphate possessed some gliding properties. For the solution, real amount of the sulphide was less than the added amount. Thiosulphate had a tendency to convert into sulphite.

AB - Interactions of certain stainless steels (S30400, S31600, S31803, S32304) and sulphur anions, separately and in combination, at concentrations typical of kraft liquors were investigated using XRF and CER techniques. IC, ISE and ABC titration were applied in the modelling of behaviour of the sulphur anions. Nickel and sulphur enriched to the steel surfaces in all experiments. Abilities of molybdenum and chromium to remain in the surfaces appeared to be better than those of iron. Adhesion of sulphur onto austenitic grades was probably stronger than that of the duplex grades. Sulphide and combination of sulphur anions formed durable films, but films formed by thiosulphate possessed some gliding properties. For the solution, real amount of the sulphide was less than the added amount. Thiosulphate had a tendency to convert into sulphite.

UR - http://www.scopus.com/inward/record.url?scp=0000590128&partnerID=8YFLogxK

U2 - 10.1002/1521-4176(200107)52:7<531::aid-maco531>3.0.co;2-s

DO - 10.1002/1521-4176(200107)52:7<531::aid-maco531>3.0.co;2-s

M3 - Article

AN - SCOPUS:0000590128

SN - 0043-2822

VL - 52

SP - 531

EP - 539

JO - Materials and Corrosion - Werkstoffe und Korrosion

JF - Materials and Corrosion - Werkstoffe und Korrosion

IS - 7

ER -

Interactions of sulphur anions and stainless steels at kraft pulp digesting temperature

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this